Two pressure-induced structural phase transitions in TiOCl

被引:4
|
作者
Ebad-Allah, J. [1 ]
Schoenleber, A. [2 ]
van Smaalen, S. [2 ]
Hanfland, M. [3 ]
Klemm, M. [1 ]
Horn, S. [1 ]
Glawion, S. [4 ]
Sing, M. [4 ]
Claessen, R. [4 ]
Kuntscher, C. A. [1 ]
机构
[1] Univ Augsburg, D-86135 Augsburg, Germany
[2] Univ Bayreuth, Lab Crystallog, D-95440 Bayreuth, Germany
[3] European Synchrotron Radiat Facil, F-38043 Grenoble, France
[4] Univ Wurzburg, D-97074 Wurzburg, Germany
来源
PHYSICAL REVIEW B | 2010年 / 82卷 / 13期
关键词
EXTERNAL-PRESSURE; TIOBR;
D O I
10.1103/PhysRevB.82.134117
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We studied the crystal structure of TiOCl up to pressures of p = 25 GPa at room temperature by x-ray powder-diffraction measurements. Two pressure-induced structural phase transitions are observed: at p(c1) approximate to 15 GPa emerges an 2a x 2b x c superstructure with b-axis unique monoclinic symmetry (space group P2(1)/m). At p(c2) approximate to 22 GPa, all lattice parameters of the monoclinic phase show a pronounced anomaly. A fraction of the sample persists in the ambient orthorhombic phase (space group Pmmn) over the whole pressure range.
引用
收藏
页数:5
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