Formation and Structural Characterization of Metal Complexes derived from Thiosalicylic Acid

被引：6
作者：
Bhowon, Minu G. [1 ]
Jhaumeer-Laulloo, Sabina [1 ]
Moosun, Salma [1 ]
Humphreys, Lisa [3 ]
Coles, Simon [2 ]
Fowdram, Roshni [1 ]
Mungra, Evena [1 ]
机构：
[1] Univ Mauritius, Dept Chem, Fac Sci, Reduit 80837, Mauritius
[2] Univ Southampton, Fac Nat & Environm Sci, Chem, Southampton SO17 1BJ, Hants, England
[3] Cranfield Univ, Ctr Def Chem, Def Acad United Kingdom, Shrivenham SN6 8LA, England
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2017年 / 643卷 / 18期
关键词：
Thiosalicylic acid; Dithiodibenzoic acid; Thiodibenzoic acid; X-ray diffraction; CRYSTAL-STRUCTURES; HYDROTHERMAL SYNTHESIS; LIGANDS; ZN(II);
D O I：
10.1002/zaac.201700244
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The formation and structural aspects of some metal complexes of thiosalicylic acid (TSA) were studied. The -bridging tetra-coordinated Ru complex, [Ru(C6H4(CO2)(mu-S)(H2O)](2) (1) was formed by hydrothermal reaction of TSA with RuCl3. The complexes [M(dtdb)(phen)(H2O)](n) (2-4) (M = Zn-II, Co-II, Ni-II, dtdb = 2,2-dithiodibenzoate anion, phen = 1,10-phenanthroline) were obtained by the slow diffusion technique and the in situ S-S bond formation was confirmed by elemental, spectral and X-ray analysis. Reaction of TSA with CuCl2 and 2,2'-bipyridine (bipy) under the slow diffusion technique yielded the dimer [Cu(tdb)(bipy)] (5) (tdb = thiodibenzoic acid), where the in situ generation of 2,2'-thiodibenzoic acid was observed.
引用
收藏
页码：1167 / 1172
页数：6
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