Investigation of the irreversible capacity loss in the layered LiNi1/3Mn1/3Co1/3O2 cathodes

被引：80
作者：
Choi, J [1 ]
Manthiram, A [1 ]
机构：
[1] Univ Texas, Mat Sci & Engn Program, Austin, TX 78712 USA
来源：
ELECTROCHEMICAL AND SOLID STATE LETTERS | 2005年 / 8卷 / 08期
关键词：
D O I：
10.1149/1.1943567
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
The irreversible capacity (IRC) loss in the first cycle at 3.0-4.6 V of layered LiNi1/3Mn1/3Co1/3O2 cathodes has been investigated as a function of synthesis temperature (600-900 degrees C), and compared with that of LiCoO2. The IRC values in both the systems increase with decreasing synthesis temperature and show a linear relationship with the Brunauer-Emmett-Teller surface area although the increase is faster with LiCoO2. Additionally, the IRC is found to exhibit a relationship to an irreversible anodic peak observed in cyclic voltammograms at around 4.5 V, which becomes prominent with decreasing synthesis temperature and increasing Mn content in LiNi1-y-zMnyCozO2. (c) 2005 The Electrochemical Society.
引用
收藏
页码：C102 / C105
页数：4
相关论文
共 35 条
  • [1] Microscopy and spectroscopy of lithium nickel oxide-based particles used in high power lithium-ion cells
    Abraham, DP
    Twesten, RD
    Balasubramanian, M
    Kropf, J
    Fischer, D
    McBreen, J
    Petrov, I
    Amine, K
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2003, 150 (11) : A1450 - A1456
  • [2] Surface characterization of electrodes from high power lithium-ion batteries
    Andersson, AM
    Abraham, DP
    Haasch, R
    MacLaren, S
    Liu, J
    Amine, K
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2002, 149 (10) : A1358 - A1369
  • [3] The study of surface phenomena related to electrochemical lithium intercalation into LixMOy host materials (M = Ni, Mn)
    Aurbach, D
    Gamolsky, K
    Markovsky, B
    Salitra, G
    Gofer, Y
    Heider, U
    Oesten, R
    Schmidt, M
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2000, 147 (04) : 1322 - 1331
  • [4] Review of selected electrode-solution interactions which determine the performance of Li and Li ion batteries
    Aurbach, D
    [J]. JOURNAL OF POWER SOURCES, 2000, 89 (02) : 206 - 218
  • [5] Common electroanalytical behavior of Li intercalation processes into graphite and transition metal oxides
    Aurbach, D
    Levi, MD
    Levi, E
    Teller, H
    Markovsky, B
    Salitra, G
    Heider, U
    Heider, L
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1998, 145 (09) : 3024 - 3034
  • [6] New insights into the interactions between electrode materials and electrolyte solutions for advanced nonaqueous batteries
    Aurbach, D
    Markovsky, B
    Levi, MD
    Levi, E
    Schechter, A
    Moshkovich, M
    Cohen, Y
    [J]. JOURNAL OF POWER SOURCES, 1999, 81 : 95 - 111
  • [7] Formation of SEI on cycled lithium-ion battery cathodes - Soft X-ray absorption study
    Balasubramanian, M
    Lee, HS
    Sun, X
    Yang, XQ
    Moodenbaugh, AR
    McBreen, J
    Fischer, DA
    Fu, Z
    [J]. ELECTROCHEMICAL AND SOLID STATE LETTERS, 2002, 5 (01) : A22 - A25
  • [8] Comparison of the chemical stability of Li1-xCoO2 and Li1-xNi0.85Co0.15O2 cathodes
    Chebiam, RV
    Prado, F
    Manthiram, A
    [J]. JOURNAL OF SOLID STATE CHEMISTRY, 2002, 163 (01) : 5 - 9
  • [9] Soft chemistry synthesis and characterization of layered Li1-xNi1-yCoyO2-δ (0 ≤ x ≤ 1 and 0 ≤ y ≤ 1)
    Chebiam, RV
    Prado, F
    Manthiram, A
    [J]. CHEMISTRY OF MATERIALS, 2001, 13 (09) : 2951 - 2957
  • [10] Comparison of the electrochemical behaviors of stoichiometric LiNi1/3Co1/3Mn1/3O2 and lithium excess Li1.03(Ni1/3Co1/3Mn1/3)0.97O2
    Choi, J
    Manthiram, A
    [J]. ELECTROCHEMICAL AND SOLID STATE LETTERS, 2004, 7 (10) : A365 - A368
1234