Enantioselective hydrogenation of alkenes and imines by a gold catalyst

被引:118
作者
González-Arellano, C
Corma, A
Iglesias, M
Sánchez, F
机构
[1] CSIC, Inst Quim Organ Gen, E-28006 Madrid, Spain
[2] Univ Politecn Valencia, CSIC, Inst Tecnol Quim, Valencia 46022, Spain
[3] CSIC, Inst Ciencia Mat Madrid, Madrid 28049, Spain
关键词
D O I
10.1039/b505271h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new neutral dimeric gold( I) complex bearing the 1,2-bis[( 2R,5R)-2,5-dimethylphospholanebenzene] [(R,R)-Me-Duphos] ligand has been synthesized which catalyzes the asymmetric hydrogenation of alkenes and imines under mild reaction conditions.
引用
收藏
页码:3451 / 3453
页数:3
相关论文
共 31 条
[1]   Recent applications of gold catalysis in organic synthesis [J].
Arcadi, A ;
Di Giuseppe, S .
CURRENT ORGANIC CHEMISTRY, 2004, 8 (09) :795-812
[2]  
Bayler A, 1997, Z NATURFORSCH B, V52, P1477
[3]   Propeller isomerism in bis(trimesitylphosphine)gold(I), -silver(I), and -copper(I) tetrafluoroborates [J].
Bayler, A ;
Bowmaker, GA ;
Schmidbaur, H .
INORGANIC CHEMISTRY, 1996, 35 (20) :5959-5960
[4]   Four-coordinate gold(I), silver(I), and copper(I) complexes with a large-span chiral ditertiary phosphine ligand [J].
Bayler, A ;
Schier, A ;
Schmidbaur, H .
INORGANIC CHEMISTRY, 1998, 37 (17) :4353-4359
[5]   MECHANISM OF THE FORMATION OF PALLADIUM COMPLEXES SERVING AS CATALYSTS IN HYDROGENATION REACTIONS .1. REACTIONS OF COMPLEXES WITH MOLECULAR-HYDROGEN [J].
BERENBLYUM, AS ;
KNIZHNIK, AG ;
MUND, SL ;
MOISEEV, II .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1982, 234 (02) :219-235
[6]   Gold: a relatively new catalyst [J].
Bond, GC .
CATALYSIS TODAY, 2002, 72 (1-2) :5-9
[7]   PREPARATION AND USE OF C2-SYMMETRICAL BIS(PHOSPHOLANES) - PRODUCTION OF ALPHA-AMINO-ACID DERIVATIVES VIA HIGHLY ENANTIOSELECTIVE HYDROGENATION REACTIONS [J].
BURK, MJ ;
FEASTER, JE ;
NUGENT, WA ;
HARLOW, RL .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (22) :10125-10138
[8]   Modular phospholane ligands in asymmetric catalysis [J].
Burk, MJ .
ACCOUNTS OF CHEMICAL RESEARCH, 2000, 33 (06) :363-372
[9]   Asymmetric catalytic routes to chiral building blocks of medicinal interest [J].
Burk, MJ ;
Gross, MF ;
Harper, TGP ;
Kalberg, CS ;
Lee, JR ;
Martinez, JP .
PURE AND APPLIED CHEMISTRY, 1996, 68 (01) :37-44
[10]   Supported gold catalyzes the homocoupling of phenylboronic acid with high conversion and selectivity [J].
Carrettin, S ;
Guzman, J ;
Corma, A .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (15) :2242-2245