Enantioselective hydrogenation of alkenes and imines by a gold catalyst

被引:118
作者
González-Arellano, C
Corma, A
Iglesias, M
Sánchez, F
机构
[1] CSIC, Inst Quim Organ Gen, E-28006 Madrid, Spain
[2] Univ Politecn Valencia, CSIC, Inst Tecnol Quim, Valencia 46022, Spain
[3] CSIC, Inst Ciencia Mat Madrid, Madrid 28049, Spain
关键词
D O I
10.1039/b505271h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new neutral dimeric gold( I) complex bearing the 1,2-bis[( 2R,5R)-2,5-dimethylphospholanebenzene] [(R,R)-Me-Duphos] ligand has been synthesized which catalyzes the asymmetric hydrogenation of alkenes and imines under mild reaction conditions.
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页码:3451 / 3453
页数:3
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