Low-melting zwitterion: effect of oxyethylene units on thermal properties and conductivity

被引:60
作者
Yoshizawa-Fujita, Masahiro [1 ]
Tamura, Tetsuya [1 ]
Takeoka, Yuko [1 ]
Rikukawa, Masahiro [1 ]
机构
[1] Sophia Univ, Dept Mat & Life Sci, Chiyoda Ku, Tokyo 1028554, Japan
关键词
TEMPERATURE MOLTEN-SALTS; PROTIC IONIC LIQUIDS; PHYSICOCHEMICAL PROPERTIES; TRANSPORT-PROPERTIES; LITHIUM BATTERIES; ELECTROLYTES; TRANSITION; GLASSES; NEUTRALIZATION; RELAXATION;
D O I
10.1039/c0cc03754k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
An imidazolium-based zwitterion containing two oxyethylene units was obtained as a colorless liquid at room temperature. The equimolar mixture of the liquid zwitterion and lithium bis(trifluoromethylsulfonyl) amide showed an ionic conductivity of over 10(-4) S cm(-1) at 80 degrees C, which was higher than those of mixtures composed of analogous solid zwitterions.
引用
收藏
页码:2345 / 2347
页数:3
相关论文
共 51 条
  • [1] RELAXATION IN LIQUIDS, POLYMERS AND PLASTIC CRYSTALS - STRONG FRAGILE PATTERNS AND PROBLEMS
    ANGELL, CA
    [J]. JOURNAL OF NON-CRYSTALLINE SOLIDS, 1991, 131 : 13 - 31
  • [2] FORMATION OF GLASSES FROM LIQUIDS AND BIOPOLYMERS
    ANGELL, CA
    [J]. SCIENCE, 1995, 267 (5206) : 1924 - 1935
  • [3] Alkylammonium-based protic ionic liquids. II. Ionic transport and heat-transfer properties: Fragility and ionicity rule
    Anouti, Meriem
    Caillon-Caravanier, Magaly
    Le Floch, Corinne
    Lemordant, Daniel
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2008, 112 (31) : 9412 - 9416
  • [4] Ternary polymer electrolytes containing pyrrolidinium-based polymeric ionic liquids for lithium batteries
    Appetecchi, G. B.
    Kim, G. -T.
    Montanina, M.
    Carewska, M.
    Marcilla, R.
    Mecerreyes, D.
    De Meatza, I.
    [J]. JOURNAL OF POWER SOURCES, 2010, 195 (11) : 3668 - 3675
  • [5] Application of the N-propyl-N-methyl-pyrrolidinium Bis(fluorosulfonyl)imide RTIL Containing Lithium Bis(fluorosulfonyl)imide in Ionic Liquid Based Lithium Batteries
    Bhatt, Anand I.
    Best, Adam S.
    Huang, Junhua
    Hollenkamp, Anthony F.
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2010, 157 (01) : A66 - A74
  • [6] Hydrophobic, highly conductive ambient-temperature molten salts
    Bonhote, P
    Dias, AP
    Papageorgiou, N
    Kalyanasundaram, K
    Gratzel, M
    [J]. INORGANIC CHEMISTRY, 1996, 35 (05) : 1168 - 1178
  • [7] Physicochemical Characterization of Morpholinium Cation Based Protic Ionic Liquids Used As Electrolytes
    Brigouleix, Catherine
    Anouti, Meriem
    Jacquemin, Johan
    Caillon-Caravanier, Magali
    Galiano, Herve
    Lemordant, Daniel
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2010, 114 (05) : 1757 - 1766
  • [8] Composition effects on ion transport in a polyelectrolyte gel with the addition of ion dissociators
    Byrne, N
    MacFarlane, DR
    Forsyth, A
    [J]. ELECTROCHIMICA ACTA, 2005, 50 (19) : 3917 - 3921
  • [9] The zwitterion effect in ionic liquids: Towards practical rechargeable lithium-metal batteries
    Byrne, N
    Howlett, PC
    MacFarlane, DR
    Forsyth, M
    [J]. ADVANCED MATERIALS, 2005, 17 (20) : 2497 - +
  • [10] Cooper E.I., 1992, P 8 INT S MOLT SALTS