Preparation and photocatalytic activity of HC/BiOBr/Bi2WO6 microspheres

被引:5
作者
Liu, Xinyu [1 ]
Li, Heruo [1 ]
Gao, Shuang [1 ]
Jing, Xue [1 ]
Ren, Yulan [1 ,2 ]
机构
[1] Mudanjiang Normal Univ, Coll Chem & Chem Engn, Mudanjiang 157011, Heilongjiang, Peoples R China
[2] Heilongjiang Prov Key Lab Photoelect Funct Mat, Mudanjiang 157011, Heilongjiang, Peoples R China
关键词
Solvothermal; Composite; BiOBr; Bi2WO6; Photocatalyst; COMPOSITES;
D O I
10.1016/j.inoche.2022.109695
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
HC/BiOBr/Bi2WO6 microspheres are synthesized by solvothermal method. The crystal structure, morphology and optical properties of the photocatalyst are investigated by XRD, SEM, BET, UV-Vis DRS and PL. SEM shows that HC/BiOBr/Bi2WO6 is composed of a spherical structure made of stacked nanosheets. The photocatalytic activity of HC/BiOBr/Bi2WO6 microspheres can be evaluated by photodegradation of rhodamine B (RhB), methyl orange (MO) and methylene blue (MB) under visible light irradiation. The results show that the photocatalytic activity of HC/BiOBr/Bi2WO6 is significantly higher than that of single phase BiOBr or Bi2WO6. In addition, HC/BiOBr/Bi2WO6 photocatalyst also has good photostability and recyclability. After irradiation with 7 W-LED for 180 min, the photodegradation efficiency of HC/BiOBr/Bi2WO6 microspheres to 10 mg/L RhB is 98.91%, which is still 70.47% after 4 cycles of degradation. HC/BiOBr/Bi2WO6 microspheres have excellent photocatalytic activity, which is mainly attributed to the improvement of light absorption capacity and the reduction of electron hole pair recombination rate.
引用
收藏
页数:8
相关论文
共 30 条
[1]   Investigation on photocatalytic activity of ZnS/NiFe2O4 NCs under sunlight irradiation via a novel two-step synthesis approach [J].
Dharmaraja, C. ;
Nicholas, P. Emmanuel ;
Ramya, P. ;
Premkumar, I. J. Isaac ;
Vijayan, V. ;
Senthilkumar, N. .
INORGANIC CHEMISTRY COMMUNICATIONS, 2021, 126
[2]   Using wood flour waste to produce biochar as the support to enhance the visible-light photocatalytic performance of BiOBr for organic and inorganic contaminants removal [J].
Geng, Aobo ;
Xu, Lijie ;
Gan, Lu ;
Mei, Changtong ;
Wang, Linjie ;
Fang, Xingyu ;
Li, Meirun ;
Pan, Mingzhu ;
Han, Shuguang ;
Cui, Juqing .
CHEMOSPHERE, 2020, 250
[3]   Enhanced hydrogen production from water splitting by Sn-doped ZnO/BiOCl photocatalysts and Eosin Y sensitization [J].
Guo, Yarui ;
Qi, Caili ;
Lu, Bin ;
Li, Ping .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2022, 47 (01) :228-241
[4]   Preparation of flowerlike BiOBr/Bi2MoO6 composite superstructures and the adsorption behavior to dyes [J].
He, Qiong ;
Ni, Yonghong ;
Ye, Shiyong .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2017, 104 :286-292
[5]   Photocatalytic property correlated with microstructural evolution of the biochar/ZnO composites [J].
He, Ya ;
Wang, Yafei ;
Hu, Jin ;
Wang, Kaijun ;
Zhai, Youwen ;
Chen, Yuze ;
Duan, Yunbiao ;
Wang, Yutian ;
Zhang, Weijun .
JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T, 2021, 11 :1308-1321
[6]   Catalysis for biomass and CO2 use through solar energy: opening new scenarios for a sustainable and low-carbon chemical production [J].
Lanzafame, Paola ;
Centi, Gabriele ;
Perathoner, Siglinda .
CHEMICAL SOCIETY REVIEWS, 2014, 43 (22) :7562-7580
[7]   Ionic liquid assisted in-situ construction of S-scheme BiOI/Bi2WO6 heterojunctions with improved sunlight-driven photocatalytic performance [J].
Lei, Shiyun ;
Luo, Rongli ;
Li, Huan ;
Chen, Jiong ;
Zhong, Junbo ;
Li, Jianzhang .
INORGANIC CHEMISTRY COMMUNICATIONS, 2020, 121
[8]   Effects of different exposed-facets on photocatalytic activity of BiOBr/Bi2Ti2O7 heterostructure and mechanism analysis [J].
Li, Panjie ;
Jiang, Caiyun ;
Feng, Changsheng ;
Wang, Yuping .
MATERIALS CHEMISTRY AND PHYSICS, 2020, 252
[9]   Pd single-atom decorated CdS nanocatalyst for highly efficient overall water splitting under simulated solar light [J].
Li, Wei ;
Chu, Xiao-shan ;
Wang, Fei ;
Dang, Yan-yan ;
Liu, Xiao-yun ;
Ma, Teng-hao ;
Li, Jia-yuan ;
Wang, Chuan-yi .
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY, 2022, 304
[10]  
Li W, 2021, ENVIRON SCI-NANO, V8, P3655, DOI [10.1039/D1EN00801C, 10.1039/d1en00801c]