Lithium insertion in LixMn2O4, 0<x<4

被引：21

作者：

Koksbang, R ^{[1
]}

Barker, J ^{[1
]}

Saidi, MY ^{[1
]}

West, K ^{[1
]}

ZachauChristiansen, B ^{[1
]}

Skaarup, S ^{[1
]}

机构：

[1] DANISH TECH UNIV,DK-2800 LYNGBY,DENMARK

来源：

SOLID STATE IONICS | 1996年 / 83卷 / 1-2期

关键词：

intercalation; manganese oxide; over-discharge; spinel;

D O I：

10.1016/0167-2738(95)00242-1

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The electrochemical lithium insertion properties of highly crystalline LixMn2O4 are investigated in the approximate lithium insertion range 0 < x < 4. Using liquid and PEO based polymer electrolytes at room and elevated temperatures, it is shown that for this material, the reversibility of the lithium insertion/extraction reactions is better at the higher voltages (versus Li/Li+), and particularly at the 4 V plateau. The lithium insertion/extraction reaction at the 1 V plateau although essentially reversible is associated with a significant voltage hysteresis.

引用

页码：151 / 157

页数：7

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