Lithium insertion in LixMn2O4, 0<x<4

被引：21
|
作者：
Koksbang, R [1 ]
Barker, J [1 ]
Saidi, MY [1 ]
West, K [1 ]
ZachauChristiansen, B [1 ]
Skaarup, S [1 ]
机构：
[1] DANISH TECH UNIV,DK-2800 LYNGBY,DENMARK
来源：
SOLID STATE IONICS | 1996年 / 83卷 / 1-2期
关键词：
intercalation; manganese oxide; over-discharge; spinel;
D O I：
10.1016/0167-2738(95)00242-1
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The electrochemical lithium insertion properties of highly crystalline LixMn2O4 are investigated in the approximate lithium insertion range 0 < x < 4. Using liquid and PEO based polymer electrolytes at room and elevated temperatures, it is shown that for this material, the reversibility of the lithium insertion/extraction reactions is better at the higher voltages (versus Li/Li+), and particularly at the 4 V plateau. The lithium insertion/extraction reaction at the 1 V plateau although essentially reversible is associated with a significant voltage hysteresis.
引用
收藏
页码：151 / 157
页数：7
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