Synthesis and characterization of a new dioxime: thermal and magnetic behavior of its heterotrinuclear BF2+-capped complexes

被引：9

作者：

Uysal, Saban ^{[1
]}

机构：

[1] Selcuk Univ, Fac Sci, Dept Chem, TR-42031 Konya, Turkey

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2010年 / 63卷 / 13期

关键词：

BF2+-capped complex; vic-dioximes; Transition metal complexes; Salen; saloph; TRANSITION-METAL-COMPLEXES; SALOPH SCHIFF-BASES; TRINUCLEAR COMPLEXES; COPPER(II) COMPLEXES; IRON(III) SALEN; MONONUCLEAR; NICKEL(II); COBALT(II); NI(II); MONO;

D O I：

10.1080/00958972.2010.501106

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New heterotrinuclear complexes have been obtained from dinuclear Fe(III) oxygen-bridged N,N'-bis(salicylidene)ethylenediamine (salenH(2)) and bis(salicylidene)-o-phenylenediamine (salophH(2)) and Co(II), Ni(II), Cu(II) salts. Then, heterotrinuclear vic-dioxime complexes containing BF2+ caps have been synthesized. The complexes have been characterized as low-spin distorted octahedral Fe(III) bridged by COO- groups. The structure of dioxime and its complexes were identified by using elemental analysis, magnetic susceptibility, thermal analysis, ICP-AES, 1H-NMR, and IR spectral data.

引用

页码：2370 / 2378

页数：9

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