Recent Advances and Perspective on Electrochemical Ammonia Synthesis under Ambient Conditions

被引：68

作者：

Li, Yang ^{[1
,2
]}

Zhang, Qi ^{[1
]}

Mei, Zongwei ^{[2
]}

Li, Shunning ^{[2
]}

Luo, Wenbin ^{[1
]}

Pan, Feng ^{[2
]}

Liu, Huakun ^{[1
]}

Dou, Shixue ^{[1
]}

机构：

[1] Univ Wollongong, Inst Superconducting & Elect Mat, Wollongong, NSW 2522, Australia

[2] Peking Univ, Shenzhen Grad Sch, Sch Adv Mat, Shenzhen 518055, Peoples R China

来源：

SMALL METHODS | 2021年 / 5卷 / 11期

基金：

澳大利亚研究理事会; 国家重点研发计划;

关键词：

electrocatalysis; electrochemical ammonia synthesis; material design strategies; reaction mechanisms; ELECTROCATALYTIC N-2 REDUCTION; EVANS-POLANYI RELATION; NITROGEN REDUCTION; ATMOSPHERIC-PRESSURE; LOW-TEMPERATURE; CATALYTIC-REDUCTION; NITRATE REDUCTION; ATOM CATALYSTS; EFFICIENT ELECTROCATALYST; HYDROGEN EVOLUTION;

D O I：

10.1002/smtd.202100460

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Ammonia is an essential chemical for agriculture and industry. To date, NH3 is mainly supplied by the traditional Haber-Bosch process, which is operated under high-temperature and high-pressure in a centralized way. To achieve ammonia production in an environmentally benign way, electrochemical NH3 synthesis under ambient conditions has become the frontier of energy and chemical conversion schemes, as it can be powered by renewable energy and operates in a decentralized way. The recent progress on developing different strategies for NH3 production, including 1) classic NH3 synthesis pathways over nanomaterials; 2) the Mars-van Krevelen (MvK) mechanism over metal nitrides (MNx); 3) reducing the nitrate into NH3 over Cu-based nanomaterial; and 4) metal-N-2 battery release of NH3 from LixM. Moreover, the most recent advances in engineering strategies for developing highly active materials and the design of the reaction systems for NH3 synthesis are covered.

引用

页数：24

共 225 条

[1] Electrochemical synthesis of ammonia via Mars-van Krevelen mechanism on the (111) facets of group III-VII transition metal mononitrides [J].

Abghoui, Younes ;

Skulason, Egill .

CATALYSIS TODAY, 2017, 286 :78-84

[2] Onset potentials for different reaction mechanisms of nitrogen activation to ammonia on transition metal nitride electro-catalysts [J].

Abghoui, Younes ;

Skulason, Egill .

CATALYSIS TODAY, 2017, 286 :69-77

[3] Electroreduction of N2 to Ammonia at Ambient Conditions on Mononitrides of Zr, Nb, Cr, and V: A DFT Guide for Experiments [J].

Abghoui, Younes ;

Garden, Anna L. ;

Howat, Jakob G. ;

Vegge, Tejs ;

Skulason, Egill .

ACS CATALYSIS, 2016, 6 (02) :635-646

[4] Enabling electrochemical reduction of nitrogen to ammonia at ambient conditions through rational catalyst design [J].

Abghoui, Younes ;

Garden, Anna L. ;

Hlynsson, Valtyr Freyr ;

Bjorgvinsdottir, Snaedis ;

Olafsdottir, Hrefna ;

Skulason, Egill .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2015, 17 (07) :4909-4918

[5] Scaling properties of adsorption energies for hydrogen-containing molecules on transition-metal surfaces [J].

Abild-Pedersen, F. ;

Greeley, J. ;

Studt, F. ;

Rossmeisl, J. ;

Munter, T. R. ;

Moses, P. G. ;

Skulason, E. ;

Bligaard, T. ;

Norskov, J. K. .

PHYSICAL REVIEW LETTERS, 2007, 99 (01)

[6]

Amar IA, 2015, INT J ELECTROCHEM SC, V10, P3757

[7] Solid-state electrochemical synthesis of ammonia: a review [J].

Amar, Ibrahim A. ;

Lan, Rong ;

Petit, Christophe T. G. ;

Tao, Shanwen .

JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2011, 15 (09) :1845-1860

[8] A rigorous electrochemical ammonia synthesis protocol with quantitative isotope measurements [J].

Andersen, Suzanne Z. ;

Colic, Viktor ;

Yang, Sungeun ;

Schwalbe, Jay A. ;

Nielander, Adam C. ;

McEnaney, Joshua M. ;

Enemark-Rasmussen, Kasper ;

Baker, Jon G. ;

Singh, Aayush R. ;

Rohr, Brian A. ;

Statt, Michael J. ;

Blair, Sarah J. ;

Mezzavilla, Stefano ;

Kibsgaard, Jakob ;

Vesborg, Peter C. K. ;

Cargnello, Matteo ;

Bent, Stacey F. ;

Jaramillo, Thomas F. ;

Stephens, Ifan E. L. ;

Norskov, Jens K. ;

Chorkendorff, Ib .

NATURE, 2019, 570 (7762) :504-+

[9] Catalytic conversion of nitrogen to ammonia by an iron model complex [J].

Anderson, John S. ;

Rittle, Jonathan ;

Peters, Jonas C. .

NATURE, 2013, 501 (7465) :84-+

[10] Oxygen Reduction Reaction Activity for Strain-Controlled Pt-Based Model Alloy Catalysts: Surface Strains and Direct Electronic Effects Induced by Alloying Elements [J].

Asano, Masato ;

Kawamura, Ryutaro ;

Sasakawa, Ren ;

Todoroki, Naoto ;

Wadayama, Toshimasa .

ACS CATALYSIS, 2016, 6 (08) :5285-5289

← 1 2 3 4 5 6 7 8 9 10 →