Recent progress of luminescent metal complexes with photochromic units

被引：173
作者：
Hasegawa, Yasuchika [1 ]
Nakagawa, Tetsuya [1 ]
Kawai, Tsuyoshi [1 ]
机构：
[1] Nara Inst Sci & Technol, Grad Sch Mat Sci, Nara 6300101, Japan
来源：
COORDINATION CHEMISTRY REVIEWS | 2010年 / 254卷 / 21-22期
关键词：
Photochromism; Emission; Luminescence; Lanthanide; Europium; Transition metal; MLCT; f orbitals; CONTAINING 1,10-PHENANTHROLINE LIGAND; INTRAMOLECULAR MAGNETIC INTERACTION; CONTAINING IONIC LIQUIDS; LANTHANIDE COMPLEXES; DIARYLETHENE DERIVATIVES; CONDUCTING POLYMER; INTENSITY PARAMETERS; ENERGY-TRANSFER; PORPHYRINIC DITHIENYLETHENE; ELECTROCHEMICAL PROPERTIES;
D O I：
10.1016/j.ccr.2009.12.036
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Photo-responsive molecules have been studied extensively because of their light irradiation abilities that enable modulation of certain physical and chemical properties in emerging molecular electronic and photonic devices. For advanced photonic applications, photochromic metal complexes that have photochromic units as the photo-responsive ligand are highly desirable, as they allow improvement of the photochromic properties and their photo-switching functionality. This article focuses on recent progress in luminescent metal complexes with photochromic units. Luminescence-switching properties of photochromic metal complexes depend on characteristic electronic transitions. The electronic transitions of photochromic metal complexes can be divided into three categories: (1) pi-pi* transition of the ligand, (2) metal to ligand charge transfer (MLCT) in transition-metal complex, and (3) f-f transition in lanthanide complex. Luminescence modulation using various metal complexes with photochromic units has been studied extensively in recent years, and various applications for future molecular switching devices are expected in the field of advanced photonics. Based on the literature and our studies on luminescent metal complexes with photochromic units, we report on the recent progress of luminescent metal complexes with photochromic units. (C) 2010 Elsevier B.V. All rights reserved.
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页码：2643 / 2651
页数：9
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