Degenerate and non-degenerate In2O3 thin films by pulsed electron beam deposition

Pulsed electron beam deposition (PED) was used to grow indium oxide thin films on c-cut sapphire single crystalline substrates between room temperature and 500 degrees C under oxygen gas. A slight difference in oxygen pressure during the PED growth (from 2 x 10(-2 )to 1.3 x 10(-2) mbar) has strong effects on the electrical and optical film properties. The indium oxide thin films grown in these conditions changed from a non-degenerate semiconducting behaviour (at 2 x 10(-2 )mbar) to a degenerate semiconductor one (at 1.3 x 10(-2 )mbar), with a metal-insulator transition at 149 K. This crossover from strong to weak localization, evidenced in the temperature dependent resistivity curves, may be due to the effects of a structural disorder in such films. The direct optical band gap was estimated from transmission spectra taking into account non-degenerate/degenerate behaviour.