Photopatternable Poly(4-styrene sulfonic acid)-Wrapped MWNT Thin-Film Source/Drain Electrodes for Use in Organic Field-Effect Transistors

被引：35

作者：

Hong, Kipyo ^{[1
]}

Kim, Se Hyun ^{[1
]}

Yang, Chanwoo ^{[1
]}

Yun, Won Min ^{[1
]}

Nam, Sooji ^{[1
]}

Jang, Jaeyoung ^{[1
]}

Park, Chanjun ^{[2
]}

Park, Chan Eon ^{[1
]}

机构：

[1] Pohang Univ Sci & Technol, Dept Chem Engn, Polymer Res Inst, Pohang 790784, South Korea

[2] Seoul Natl Univ Sci & Technol, Dept Mech Engn, Seoul 139743, South Korea

来源：

ACS APPLIED MATERIALS & INTERFACES | 2011年 / 3卷 / 01期

关键词：

solution-processable; photopatternable; source/drain electrode; carbon nanotube; organic field-effect transistor; contact resistance; WALLED CARBON NANOTUBES; LARGE-AREA; POLYMER; PENTACENE; WATER; SOLUBILIZATION; TRANSPARENT; INTERFACES; MOBILITY; BARRIER;

D O I：

10.1021/am1008826

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

We describe the cross linking of poly(4-styrene-sulfonic cid) (PSS) by exposure to ultra violet (UV) light (lambda = 255 nm) under a vacuum. Fourier transform infrared (FT-IR) spectroscopy and X-ray photoelectron spectroscopy (XPS) showed that the photo-crosslinking of PSS resulted from coupling between radicals that were generated in the polymer chains by UV excitation.The photo-cross-linkable characteristics of PSS Were employed to fabricate solution-processable, Photopatternable, and conductive PSS-wrapped multiwalled carbon nanotube (MWNT) composite thin films by wrapping MWNTs with PSS in water. During photo-cross-linking, the work function of the PSS-wrapped MWNTs decreased from 4.83 to 4.53 eV following cleavage of a significant number of sulfonic acid groups. Despite the decreased work function of the PSS wrapped MWNTs the photopatterned PSS wrapped MWNTs produced good source/drain electrodes for OFETs, yeilding a mobility (0.134 +/- 0.056 cm(2)/(V s)) for the TIPS-PEN field-effect transistors fabricated using PSS-wrapped MWNTs as source/drain electrodes that was higher the mobility of gold-based transistors (0.01,1 +/- 0.004 cm(2)/(V s))

引用

页码：74 / 79

页数：6

共 47 条

[1] Carbon nanotube sheets as electrodes in organic light-emitting diodes [J].

Aguirre, CM ;

Auvray, S ;

Pigeon, S ;

Izquierdo, R ;

Desjardins, P ;

Martel, R .

APPLIED PHYSICS LETTERS, 2006, 88 (18)

[2] Nanometre-size tubes of carbon [J].

Ajayan, PM ;

Ebbesen, TW .

REPORTS ON PROGRESS IN PHYSICS, 1997, 60 (10) :1025-1062

[3]

[Anonymous], INFRARED CHARACTERIS

[4] Functionalized pentacene: Improved electronic properties from control of solid-state order [J].

Anthony, JE ;

Brooks, JS ;

Eaton, DL ;

Parkin, SR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (38) :9482-9483

[5] High-performance plastic transistors fabricated by printing techniques [J].

Bao, ZN ;

Feng, Y ;

Dodabalapur, A ;

Raju, VR ;

Lovinger, AJ .

CHEMISTRY OF MATERIALS, 1997, 9 (06) :1299-&

[6] Electron energetics at surfaces and interfaces: Concepts and experiments [J].

Cahen, D ;

Kahn, A .

ADVANCED MATERIALS, 2003, 15 (04) :271-277

[7]

Cheremisinoff N.P., 1989, HDB POLYM SCI TECHNO

[8] IMPRINT OF SUB-25 NM VIAS AND TRENCHES IN POLYMERS [J].

CHOU, SY ;

KRAUSS, PR ;

RENSTROM, PJ .

APPLIED PHYSICS LETTERS, 1995, 67 (21) :3114-3116

[9] Field effect transport measurements on single grains of sexithiophene: Role of the contacts [J].

Chwang, AB ;

Frisbie, CD .

JOURNAL OF PHYSICAL CHEMISTRY B, 2000, 104 (51) :12202-12209

[10] Large-scale complementary integrated circuits based on organic transistors [J].

Crone, B ;

Dodabalapur, A ;

Lin, YY ;

Filas, RW ;

Bao, Z ;

LaDuca, A ;

Sarpeshkar, R ;

Katz, HE ;

Li, W .

NATURE, 2000, 403 (6769) :521-523

← 1 2 3 4 5 →