Redox Control in Olefin Polymerization and Copolymerization

被引:23
作者
Chen, Min [1 ]
Yang, Bangpei [1 ]
Chen, Changle [1 ]
机构
[1] Univ Sci & Technol China, Dept Polymer Sci & Engn, Chinese Acad Sci, Key Lab Soft Matter Chem, Hefei 230026, Peoples R China
基金
中国国家自然科学基金; 高等学校博士学科点专项科研基金;
关键词
olefin polymerization; polar monomer; redox control; palladium catalysis; switchable polymerization; INSERTION POLYMERIZATION; ETHYLENE POLYMERIZATION; BIS(IMINO)PYRIDINE IRON; CHAIN TRANSFER; COMPLEXES; CATALYSTS; LIGAND; LACTIDE; NICKEL; SUPPRESSION;
D O I
10.1055/s-0035-1561368
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
In the field of olefin polymerization, catalyst modification remains the prevalent strategy to control the polymerization and copolymerization processes. The development of alternative strategies is, nevertheless, highly fascinating. Here, the concept of redox-controlled polymerization and its applications in the ring-opening polymerization of cyclic ester type monomers is presented. Early work on the introduction of the redox-control concept into the field of olefin polymerization is described, and our approach to address the early issues and realize redox controlled olefin polymerization and copolymerization is demonstrated. Finally, some conclusions and perspectives are discussed. 1 Introduction 2 The Concept of Redox Control in Polymerization 3 Early Work on Redox Control in Olefin Polymerization 4 Our Approach to Realize Redox-Controlled Olefin (Co)Polymerization 5 Conclusions and Perspectives
引用
收藏
页码:1297 / 1302
页数:6
相关论文
共 51 条
[1]   Redox-Active Ligands: An Advanced Tool To Modulate Polyethylene Microstructure [J].
Anderson, W. Curtis, Jr. ;
Rhinehart, Jennifer L. ;
Tennyson, Andrew G. ;
Long, Brian K. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2016, 138 (03) :774-777
[2]   Catalytic production of olefin block copolymers via chain shuttling polymerization [J].
Arriola, DJ ;
Carnahan, EM ;
Hustad, PD ;
Kuhlman, RL ;
Wenzel, TT .
SCIENCE, 2006, 312 (5774) :714-719
[3]   Redox-Controlled Polymerization of Lactide Catalyzed by Bis(imino)pyridine Iron Bis(alkoxide) Complexes [J].
Biernesser, Ashley B. ;
Li, Bo ;
Byers, Jeffery A. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (44) :16553-16560
[4]   Constrained geometry complexes - Synthesis and applications [J].
Braunschweig, Holger ;
Breitling, Frank M. .
COORDINATION CHEMISTRY REVIEWS, 2006, 250 (21-22) :2691-2720
[5]   Redox control of a polymerization catalyst by changing the oxidation state of the metal center [J].
Broderick, Erin M. ;
Guo, Neng ;
Wu, Tianpin ;
Vogel, Carola S. ;
Xu, Cuiling ;
Sutter, Joerg ;
Miller, Jeffrey T. ;
Meyer, Karsten ;
Cantat, Thibault ;
Diaconescu, Paula L. .
CHEMICAL COMMUNICATIONS, 2011, 47 (35) :9897-9899
[6]   Redox Control of a Ring-Opening Polymerization Catalyst [J].
Broderick, Erin M. ;
Guo, Neng ;
Vogel, Carola S. ;
Xu, Cuiling ;
Sutter, Joerg ;
Miller, Jeffrey T. ;
Meyer, Karsten ;
Mehrkhodavandi, Parisa ;
Diaconescu, Paula L. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (24) :9278-9281
[7]   Effects of Ferrocenyl Proximity and Monomer Presence during Oxidation for the Redox-Switchable Polymerization of L-Lactide [J].
Brown, Lauren A. ;
Rhinehart, Jennifer L. ;
Long, Brian K. .
ACS CATALYSIS, 2015, 5 (10) :6057-6060
[8]   Designing late-transition metal catalysts for olefin insertion polymerization and copolymerization [J].
Camacho, Drexel H. ;
Guan, Zhibin .
CHEMICAL COMMUNICATIONS, 2010, 46 (42) :7879-7893
[9]   Transition-Metal-Catalyzed Functional Polyolefin Synthesis: Effecting Control through Chelating Ancillary Ligand Design and Mechanistic Insights [J].
Carrow, Brad P. ;
Nozaki, Kyoko .
MACROMOLECULES, 2014, 47 (08) :2541-2555
[10]   Multiple insertion of a silyl vinyl ether by (α-diimine)PdMe+ species [J].
Chen, Changle ;
Luo, Shuji ;
Jordan, Richard F. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (39) :12892-+