{Bis[2-(3,5-dimethylpyrazol-1-yl-κN2)ethyl]amine-κN}chloridopalladium(II)chloride 0.25-hydrate

被引：2

作者：

Guzei, Ilia A. ^{[1
,2
]}

Spencer, Lara C. ^{[1
]}

Miti, Nangamso ^{[2
]}

Darkwa, James ^{[2
]}

机构：

[1] Univ Wisconsin, Dept Chem, Madison, WI 53706 USA

[2] Univ Johannesburg, Dept Chem, ZA-2006 Auckland Pk, South Africa

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷

关键词：

ETHYLENE; CATALYSTS;

D O I：

10.1107/S1600536810035427

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, [PdCl(C14H23N5)] Cl.0.25H(2)O, is a pseudopolymorph of the previously reported compound [PdCl(C14H23N5)] Cl.0.25H(2)O [de Mendoza et al. (2006). Acta Cryst. E62, m2934-m2936]. The cationic complex and chloride anion are disordered over two positions each in a 0.584 (4): 0.416 (4) ratio. The geometry about the Pd atom is distorted square-planar. The pyrazole rings are almost perpendicular, forming a dihedral angle of 86.6 (6)degrees to each other, to mitigate steric conflict between their methyl groups.

引用

页码：M1243 / U695

页数：13

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