Controlling Porosity in Lignin-Derived Nanoporous Carbon for Supercapacitor Applications

被引:213
作者
Jeon, Ju-Won [1 ,4 ]
Zhang, Libing [2 ,3 ]
Lutkenhaus, Jodie L. [4 ]
Laskar, Dhrubojyoti D. [2 ,3 ]
Lemmon, John P. [1 ]
Choi, Daiwon [1 ]
Nandasiri, Manjula I. [1 ]
Hashmi, Ali [5 ]
Xu, Jie [6 ]
Motkuri, Radha K. [1 ]
Fernandez, Carlos A. [1 ]
Liu, Jian [1 ]
Tucker, Melvin P. [7 ]
McGrail, Peter B. [1 ]
Yang, Bin [2 ,3 ]
Nune, Satish K. [1 ]
机构
[1] Pacific NW Natl Lab, Energy & Environm Directorate, Richland, WA 99354 USA
[2] Washington State Univ, Richland, WA 99354 USA
[3] Washington State Univ, Bioprod Sci & Engn Lab, Richland, WA 99354 USA
[4] Texas A&M Univ, Artie McFerrin Dept Chem Engn, College Stn, TX 77843 USA
[5] Washington State Univ, Dept Mech Engn, Vancouver, WA 98686 USA
[6] Univ Illinois, Dept Mech & Ind Engn, Chicago, IL 60607 USA
[7] Natl Renewable Energy Lab, Natl Bioenergy Ctr, Golden, CO 80401 USA
关键词
carbonization; lignin; porous carbon; supercapacitor; sustainable materials; ACTIVATED CARBON; POROUS CARBON; MESOPOROUS CARBONS; CATHODE MATERIALS; MOLECULAR-WEIGHT; HIGH-POWER; PERFORMANCE; ADSORPTION; ELECTRODES; NANOTUBE;
D O I
10.1002/cssc.201402621
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Low-cost renewable lignin has been used as a precursor to produce porous carbons. However, to date, it has not been easy to obtain high surface area porous carbon without activation processes or templating agents. Here, we demonstrate that low molecular weight lignin yields highly porous carbon with more graphitization through direct carbonization without additional activation processes or templating agents. We found that molecular weight and oxygen consumption during carbonization are critical factors to obtain high surface area, graphitized porous carbons. This highly porous carbon from low-cost renewable lignin sources is a good candidate for supercapacitor electrode materials.
引用
收藏
页码:428 / 432
页数:5
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