Synthesis of vinylsulfonyl(halo)pyridines and their reactions with binucleophilic reagents

被引：1

作者：

Amosova, SV ^{[1
]}

Gavrilova, GM ^{[1
]}

机构：

[1] Russian Acad Sci, Siberian Div, Faworsky Irkutsk Inst Chem, Irkutsk 664033, Russia

来源：

RUSSIAN JOURNAL OF ORGANIC CHEMISTRY | 2004年 / 40卷 / 11期

基金：

俄罗斯基础研究基金会;

关键词：

Oxidation; Hydrogen; Acetic; Hydrogen Peroxide; Organic Chemistry;

D O I：

10.1007/s11178-005-0075-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Oxidation of vinylthio(halo)pyridines with 30-33% hydrogen peroxide solution in acetic anhydride at 20-25degreesC furnished vinylsulfonyl(hato)pyridines. Nucleophilic addition reactions of 2-amino-1-ethanethio hydrochloride and thiosemicarbazide to the multiple bonds of vinylsulfonyl(halo)pyridines were per-formed.

引用

页码：1657 / 1661

页数：5

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