Formation of a novel hexanuclear ZrIV cage compound with bridging chelating ligand: [(CpZr)6(μ-O2C-C6H2Cl2-2-O)9(OH2)3]•H2O

被引：3
作者：
Li, Jinling [1 ,2 ]
Gao, Ziwei [1 ,2 ]
Han, Li [1 ,2 ]
Gao, Lingxiang [1 ,2 ]
Zhang, Guofang [1 ,2 ]
Tikkanen, Wayne [3 ]
机构：
[1] Shaanxi Normal Univ, Minist Educ, Key Lab Appl Surface & Colloid Chem, Xian 710062, Peoples R China
[2] Shaanxi Normal Univ, Sch Chem & Mat Sci, Xian 710062, Peoples R China
[3] Calif State Univ Los Angeles, Dept Chem & Biochem, Los Angeles, CA 90032 USA
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2010年 / 695卷 / 15-16期
基金：
中国国家自然科学基金;
关键词：
Cage compound; Aqueous medium synthesis; Carboxylate ligands; Half-sandwich compound; Zirconium; COMPLEXES; CLUSTERS; ENCAPSULATION; CORE; DISPROPORTIONATION; DIMERIZATION; DERIVATIVES; CARBOXYLATE; HYDROXIDE; OXIDES;
D O I：
10.1016/j.jorganchem.2010.04.035
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of Cp2ZrCl2 with 3,5-dicholorosalicylic acid in a CH2Cl2-Et2O system containing HCl (1.0 mol L-1), gives a cage half-sandwich cyclopentadienyl-zirconocene compound, [(CpZr)(6)(mu-O2C-C6H2Cl2-2-O)(9)(OH2)(3)]center dot H2O (1). The crystal structure of 1 shows a twisted tripyramidal prism cage structure with one water molecule in the cage's cavity. In the cage, the dianionic, substituted salicylate ligands adopt a bridging chelate mu(2)-(O, O', O '') coordination mode. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码：1848 / 1851
页数：4
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