New conducting co-ordination polymers containing M(dmit)2 links

被引：15

作者：

Cerrada, E ^{[1
]}

Diaz, MC ^{[1
]}

Diaz, C ^{[1
]}

Laguna, M ^{[1
]}

Sabater, A ^{[1
]}

机构：

[1] Univ Zaragoza, CSIC, Inst Ciencia Mat Aragon, Escuela Univ Huesca, E-50009 Zaragoza, Spain

来源：

SYNTHETIC METALS | 2001年 / 119卷 / 1-3期

关键词：

conducting polymers; dmit derivatives;

D O I：

10.1016/S0379-6779(00)00847-X

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The reaction of [M(dmit)(P-P)] (P-P = dppm, dppe) (dmit = 1,3-dithiol-2-thione-4,5-dimercapto, dppe = bis-(diphenylphosphine)ethane, dppm = bis-(diphenylphosphine)methane) with gold, silver and copper salts provides trinuclear derivatives with the general formula [M ' {M(dmit)(P-P)}(2)] (M = Ni, Pd; M ' = Cu, Ag, Au). The same type of reactions starting with [M(dmit)(2)](n-) (M = Ni, Au) gave conducting polymers with different stoichiometry depending on the metal and the reaction conditions.

引用

页码：91 / 92

页数：2

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