Toward an understanding of the global atmospheric distribution of persistent organic pollutants: The use of semipermeable membrane devices as time-integrated passive samplers

被引:126
作者
Ockenden, WA [1 ]
Sweetman, AJ
Prest, HF
Steinnes, E
Jones, KC
机构
[1] Univ Lancaster, IENS, Dept Environm Sci, Lancaster LA1 4YQ, England
[2] Univ Calif Santa Cruz, Inst Marine Sci, LML, Santa Cruz, CA 95060 USA
[3] Norwegian Univ Sci & Technol, Dept Chem, N-7034 Trondheim, Norway
关键词
D O I
10.1021/es9802145
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Triolein-containing semipermeable membrane devices (SPMDs) were deployed as passive air samplers alongside conventional air samplers at two sites, and derived atmospheric concentrations from each were compared. Excellent comparability was noted between sampling systems. SPMDs were also deployed for 2 years at 10 sites across a latitudinal transect from the south of the U.K. (ca. 50 degrees N) to the north of Norway (ca. 70 degrees N) to passively sample air. Time-integrated, simultaneous data were obtained, which were used to test the global fractionation hypothesis in the Northern Hemisphere. Extracts were analyzed for a suite of PCB congeners and alpha- and gamma-HCH. A latitudinal change in PCB profiles was seen. The absolute atmospheric concentration of the tetra-chlorinated PCBs was relatively uniform over the study area (ca. 1.9 pg m(-3)), but their relative concentration increased with increasing latitude or decreasing temperature (12% of total PCB concentrations in the south of the U.K. as compared with 35% at the northern-most station). The concentration of the penta-chlorinated PCBs decreased from 6 pg m(-3) at the southern U.K. site to 1.5 pg m(-3) in the north of Norway, but their relative concentration was uniform (33% total PCB) over the transect. Absolute and relative concentrations of heavier PCBs decreased with increasing latitude and decreasing temperature. These data indicate that a temperature-controlled fractionation of PCBs is occurring in the atmosphere. Data were available for soil PCB concentrations at or near seven of the air sampling sites. Fugacity quotients suggested that across the study area the air/soil system is at or near to equilibrium for PCBs. Concentrations of the alpha-HCH isomer sequestered by the SPMDs increased from south to north while the sequestered gamma-HCH concentrations decreased. The ratio of alpha/gamma-HCH increased by a factor of approximately 20 from the south to the north of the study area, These data are consistent with the selective weathering of these compounds during their long-range atmospheric transport from southerly source regions to remote northern locations.
引用
收藏
页码:2795 / 2803
页数:9
相关论文
共 39 条
[1]   LONG-TERM CHANGES IN THE POLYCHLORINATED BIPHENYL CONTENT OF UNITED-KINGDOM SOILS [J].
ALCOCK, RE ;
JOHNSTON, AE ;
MCGRATH, SP ;
BERROW, ML ;
JONES, KC .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1993, 27 (09) :1918-1923
[2]   Synchronous or clear-path control in personal rapid transit systems [J].
Anderson, JE .
JOURNAL OF ADVANCED TRANSPORTATION, 1996, 30 (03) :1-3
[3]   ORGANOCHLORINE PESTICIDES IN THE ATMOSPHERE OF THE SOUTHERN-OCEAN AND ANTARCTICA, JANUARY MARCH, 1990 [J].
BIDLEMAN, TF ;
WALLA, MD ;
ROURA, R ;
CARR, E ;
SCHMIDT, S .
MARINE POLLUTION BULLETIN, 1993, 26 (05) :258-262
[4]   EVIDENCE FOR SHORT-RANGE TRANSPORT OF POLYCHLORINATED-BIPHENYLS IN THE CANADIAN ARCTIC USING CONGENER SIGNATURES OF PCBS IN SOILS [J].
BRIGHT, DA ;
DUSHENKO, WT ;
GRUNDY, SL ;
REIMER, KJ .
SCIENCE OF THE TOTAL ENVIRONMENT, 1995, 160-61 :251-263
[5]   PARTITION-COEFFICIENTS OF ORGANIC-COMPOUNDS IN LIPID WATER-SYSTEMS AND CORRELATIONS WITH FISH BIOCONCENTRATION FACTORS [J].
CHIOU, CT .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1985, 19 (01) :57-62
[6]  
COUSINS IT, IN PRES ENV POLLUT
[7]   VAPOR-PRESSURES AND PREDICTED PARTICLE GAS DISTRIBUTIONS OF POLYCHLORINATED BIPHENYL CONGENERS AS FUNCTIONS OF TEMPERATURE AND ORTHO-CHLORINE SUBSTITUTION [J].
FALCONER, RL ;
BIDLEMAN, TF .
ATMOSPHERIC ENVIRONMENT, 1994, 28 (03) :547-554
[8]   PCBS IN UK URBAN AIR [J].
HALSALL, CJ ;
LEE, RGM ;
COLEMAN, PJ ;
BURNETT, V ;
HARDINGJONES, P ;
JONES, KC .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1995, 29 (09) :2368-2376
[9]   Measurements of octanol-air partition coefficients for polychlorinated biphenyls [J].
Harner, T ;
Bidleman, TF .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1996, 41 (04) :895-899
[10]   MODEL OF THE LONG-TERM EXCHANGE OF PCBS BETWEEN SOIL AND THE ATMOSPHERE IN THE SOUTHERN UK [J].
HARNER, T ;
MACKAY, D ;
JONES, KC .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1995, 29 (05) :1200-1209