X-ray crystallographic and spectroscopic investigations of copper(II) nitrate-1-allylimidazole complexes

被引:0
|
作者
Kurdziel, K
Glowiak, T
机构
[1] Jan Kochanowski Univ Humanities & Sci, Inst Chem, PL-25020 Kielce, Poland
[2] Univ Wroclaw, Fac Chem, PL-50383 Wroclaw, Poland
关键词
copper(II) complexes; 1-allylimidazole complexes; spectra; crystal structures; magnetic properties;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Copper(II) complexes Cu(2)L(4)(NO(3))(4) (a) and CuL(4)(NO(3))(2) (b), where L is 1-allylimidazole, have been synthesized and characterized by elemental analysis, IR, FTIR, near IR, VIS, magnetic and crystallographic measurements. In centrosymmetric binuclear complex (a) the nitrate anions are linked to the Cu(II) cations through bidentate oxygen atoms. In complex (b) the Cu(II) cation occupies a symmetry centre and is tetragonal-bipyramid coordinated.
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页码:2181 / 2188
页数:8
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