Synthesis and Crystal Structure of a Novel 1,3,4-Oxadiazin-one Compound

被引:3
作者
Sun, Hongshun [1 ,2 ]
Wang, Jianqiang [1 ]
Tan, Wenwen [2 ]
Yang, Haidong [2 ]
Li, Yulong [2 ]
Shen, Linjiang [1 ]
Guo, Cheng [1 ]
机构
[1] Nanjing Tech Univ, Coll Chem & Mol Engn, Nanjing 211816, Jiangsu, Peoples R China
[2] Nanjing Polytech Inst, Dept Chem Engn, Nanjing 210048, Jiangsu, Peoples R China
基金
中国国家自然科学基金;
关键词
benzothiophen; oxadiazin; synthesis; crystal structure;
D O I
10.6023/cjoc201509033
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Using benzothiophene-2-carboxylic acid as a raw material, 2-(1-benzothiophen-2-yl)-4H-1,3,4-oxadiazin-5(613)-one (4) was synthesized by esterification and hydrazinolysis, followed by the acylation and cyclization reactions. The novel compound 4 was characterized by H-1 NMR, C-13 NMR, ESI-MS, FT-IR, elemental analysis and X-ray single crystal diffraction.
引用
收藏
页码:622 / 625
页数:4
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