Novel bis-piperidinium and bis-pyrrolidinium compounds as versatile phase-transfer catalysts

被引:4
作者
Saif, Muhammad Jawwad [1 ]
Anwar, Jamil [1 ]
Munawar, Munawar Ali [1 ]
Kashif, Muhammad [1 ]
Asghar, Muhammad Imran [1 ]
机构
[1] Univ Punjab, Inst Chem, Lahore 54590, Pakistan
关键词
Bis-piperidinium; bis-pyrrolidinium; bis-quaternary ammonium; phase-transfer catalysis; QUATERNARY AMMONIUM-SALTS; SUBSTITUTION; ALKYLATION; OXIDATION;
D O I
10.3998/ark.5550190.0011.b12
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Syntheses and applications of new bis-piperidinium and bis-pyrrolidinium compounds as effective two-center phase-transfer catalysts are presented. Applications of these catalysts have been explored in etherification and N-alkylation reactions, and comparisons between these catalysts and traditional phase-transfer catalysts such as cetyltrimethylammonium bromide (CTAB) and 1-ethyl-3-methylimidazolium chloride (emim(+)Cl(-)) are presented.
引用
收藏
页码:133 / 145
页数:13
相关论文
共 23 条
[1]   Cycloalkylation reactions of fatty amines with α,ω-dihaloalkanes:: Role of bis-quaternary ammonium salts as phase-transfer catalysts [J].
Ali, Hanan El-Sharkawy .
CATALYSIS COMMUNICATIONS, 2007, 8 (06) :855-860
[2]   A gemini amphiphillic phase transfer catalyst for dark singlet oxygenation [J].
Borde, Cedric ;
Nardello, Veronique ;
Wattebled, Laurent ;
Laschewsky, Andre ;
Aubry, Jean-Marie .
JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, 2008, 21 (7-8) :652-658
[3]   Biaryl synthesis via Suzuki coupling promoted by catalytic amounts of quaternary ammonium salts [J].
Castanet, AS ;
Colobert, F ;
Desmurs, JR ;
Schlama, T .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2002, 182 (01) :481-487
[4]   SYNTHESIS OF 5-HYDROXY-1,3-BENZOXATHIOLE [J].
DEGANI, I ;
DOLCI, M ;
FOCHI, R .
SYNTHETIC COMMUNICATIONS, 1980, 10 (02) :161-166
[5]   STRUCTURE AND MAGNETIC STUDIES OF BIS-PIPERIDINIUM TETRACHLOROCUPRATE [J].
DRUMHELLER, JE ;
SEIFERT, PL ;
ZASPEL, CE ;
SNIVELY, LO ;
EMERSON, K .
JOURNAL OF CHEMICAL PHYSICS, 1980, 73 (11) :5830-5832
[6]  
FREEDMAN HH, 1975, TETRAHEDRON LETT, P3251
[7]   BIPHASIC AND PHASE-TRANSFER CATALYZED CARBONYLATION OF VINYLIC BROMIDES [J].
GALAMB, V ;
ALPER, H .
TRANSITION METAL CHEMISTRY, 1983, 8 (05) :271-273
[8]   N-alkylation of 2,4,5-triphenyl imidazole derivatives using a new phase transfer reagent under PTC conditions [J].
Jayachandran, JP ;
Wang, ML .
SYNTHETIC COMMUNICATIONS, 2001, 31 (18) :2743-2752
[9]  
Jones R.A., 2001, QUATERNARY AMMONIUM
[10]   STEREOSELECTIVE SUBSTITUTION ON PVC USING PHASE-TRANSFER CATALYSTS [J].
MARTINEZ, G ;
MIJANGOS, C ;
TERROBA, P ;
MILLAN, J .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1988, 26 (06) :1629-1637