An isoselective and visual inclusion host system using charge-transfer complexes of 3,3'-disubstituted-1,1'-bi-2-naphthol and methylviologen

被引:22
作者
Imai, Yoshitane
Kamon, Kensaku
Kinuta, Takafurni
Nobuo, Tajima
Sato, Tornohiro
Kuroda, Reiko
Matsubara, Yoshio
机构
[1] Kinki Univ, Fac Sci & Engn, Dept Appl Chem, Higashiosaka, Osaka 5778502, Japan
[2] JST ERATO SORST Kuroda Chiromorphol Team, Meguro Ku, Tokyo 1530041, Japan
[3] NIMS, Computat Mat Sci Ctr, Principles Simulat Grp 1, Tsukuba, Ibaraki 3050047, Japan
[4] Univ Tokyo, Grad Sch Arts & Sci, Dept Life Sci, Meguro Ku, Tokyo 1538902, Japan
关键词
1,1'-bi-2-naphthol; CT complex; methylviologen; molecular recognition; supramolecular complex;
D O I
10.1016/j.tetlet.2007.07.023
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A charge-transfer (CT) complex, composed of rac-3,3 '-dibromo-1,1 '-bi-2-naphthol as the electron donor and 1,1 ' dimethyl-4,4 '-bipyridinium dichloride as the electron acceptor, is formed only by the inclusion of specific guest molecules. The color of this inclusion CT complex is sensitive to the component guest molecules. (c) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码:6321 / 6325
页数:5
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