The energetics of aromatic hydrocarbons: An experimental thermochemical perspective

被引：183
作者：
Slayden, SW
Liebman, JF
机构：
[1] George Mason Univ, Dept Chem, Fairfax, VA 22030 USA
[2] Univ Maryland Baltimore Cty, Dept Chem & Biochem, Baltimore, MD 21250 USA
来源：
CHEMICAL REVIEWS | 2001年 / 101卷 / 05期
关键词：
D O I：
10.1021/cr990324+
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A thermomechanical description of the concepts, definitions and the scope of the study of aromaticity and antiaromaticity of organic compounds was presented. The discussion included examination of the enthalpies of formation of the combustion, hydrogenation and phase changes of neutral, π-conjugated, carbocyclic systems and some of their alkylated and arylated derivatives. The compounds were synthesized, isolated and characterized by their spectra, melting points and thermomechanical data.
引用
收藏
页码：1541 / 1566
页数：26
相关论文
共 155 条
[21]   MEASUREMENT AND ESTIMATION OF THE HEATS OF VAPORIZATION OF HYDROCARBONS [J].
CHICKOS, JS ;
HYMAN, AS ;
LADON, LH ;
LIEBMAN, JF .
JOURNAL OF ORGANIC CHEMISTRY, 1981, 46 (21) :4294-4296
[22]   ENTHALPIES OF VAPORIZATION OF SOME HIGHLY BRANCHED HYDROCARBONS [J].
CHICKOS, JS ;
HESSE, DG ;
HOSSEINI, S ;
LIEBMAN, JF ;
MENDENHALL, GD ;
VEREVKIN, SP ;
RAKUS, K ;
BECKHAUS, HD ;
RUCHARDT, C .
JOURNAL OF CHEMICAL THERMODYNAMICS, 1995, 27 (06) :693-705
[23]  
CHICKOS JS, COMMUNICATION
[24]   THE THERMODYNAMIC PROPERTIES OF 4,5,9,10-TETRAHYDROPYRENE AND OF 1,2,3,6,7,8-HEXAHYDROPYRENE [J].
CHIRICO, RD ;
KNIPMEYER, SE ;
NGUYEN, A ;
SMITH, NK ;
STEELE, WV .
JOURNAL OF CHEMICAL THERMODYNAMICS, 1993, 25 (06) :729-761
[25]   THE THERMODYNAMIC PROPERTIES TO THE TEMPERATURE 700 K OF NAPHTHALENE AND OF 2,7-DIMETHYLNAPHTHALENE [J].
CHIRICO, RD ;
KNIPMEYER, SE ;
NGUYEN, A ;
STEELE, WV .
JOURNAL OF CHEMICAL THERMODYNAMICS, 1993, 25 (12) :1461-1494
[26]   THE THERMODYNAMIC PROPERTIES OF 4-METHYLPHENANTHRENE [J].
CHIRICO, RD ;
HOSSENLOPP, IA ;
NGUYEN, A ;
STEELE, WV ;
GAMMON, BE .
JOURNAL OF CHEMICAL THERMODYNAMICS, 1989, 21 (02) :179-201
[27]  
Clar E., 1972, AROMATIC SEXTET
[28]   HEATS OF COMBUSTION OF BIPHENYL BIBENZYL NAPHTHALENE ANTHRACENE AND PHENANTHRENE [J].
COLEMAN, DJ ;
PILCHER, G .
TRANSACTIONS OF THE FARADAY SOCIETY, 1966, 62 (520P) :821-&
[29]  
COLOMINA M, 1979, AN QUIM, V75, P620
[30]  
Cox J.D., 1970, THERMOCHEMISTRY ORGA
12345678910