Amphiphilic multicomponent molecular brushes

被引：25

作者：

Ivanov, Ivan V. ^{[1
]}

Meleshko, Tamara K. ^{[1
]}

Kashina, Anna V. ^{[1
]}

Yakimansky, Alexander V. ^{[1
,2
]}

机构：

[1] Russian Acad Sci, Inst Macromol Cpds, Bolshoi Prosp 31, St Petersburg 199004, Russia

[2] St Petersburg State Univ, Inst Chem, Univ Skii Prosp 26, St Petersburg 198504, Peterhof, Russia

来源：

RUSSIAN CHEMICAL REVIEWS | 2019年 / 88卷 / 12期

关键词：

RING-OPENING METATHESIS; CYLINDRICAL POLYMER BRUSHES; TRANSFER RADICAL POLYMERIZATION; SIZE-EXCLUSION CHROMATOGRAPHY; FRAGMENTATION CHAIN TRANSFER; COMB BLOCK-COPOLYMERS; THERANOSTIC UNIMOLECULAR MICELLES; HIGHLY EFFICIENT SYNTHESIS; DILUTE-SOLUTION PROPERTIES; CORE-SHELL BRUSHES;

D O I：

10.1070/RCR4870

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Multicomponent molecular brushes containing amphiphilic polymer moieties are promising objects of research of macromolecular chemistry. The development of stimulus-responsive systems sensitive to changes in environmental parameters, based on the molecular brushes, opens up new possibilities for their applications in medicine, biochemistry and microelectronics. The review presents the current understanding of the structures of main types of amphiphilic multicomponent brushes, depending on the chemical nature and type of coupling of the backbone and side chains. The approaches to the controlled synthesis of multicomponent molecular brushes of different architecture are analyzed. Selfassembly processes of multicomponent molecular brushes in selective solvents are considered.

引用

页码：1248 / 1290

页数：43

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