Towards the Generation of Self-Healing Materials by Means of a Reversible Photo-induced Approach

被引：180

作者：

Froimowicz, Pablo ^{[1
]}

Frey, Holger ^{[2
]}

Landfester, Katharina ^{[1
]}

机构：

[1] Max Planck Inst Polymer Res, D-55128 Mainz, Germany

[2] Johannes Gutenberg Univ Mainz, Inst Organ Chem, D-55128 Mainz, Germany

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2011年 / 32卷 / 05期

关键词：

cycloaddition; dendritic polymers; photochemistry; reversibility; self-healing; CROSS-LINKING; HYPERBRANCHED POLYGLYCEROLS; MOLECULAR NANOCAPSULES; PHOTODIMERIZATION; HYDROGEL; POLYMERS; MOIETY;

D O I：

10.1002/marc.201000643

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Photo-induced reversibility as a tool for self-healing: a reversible photo-induced dendritic macromonomer was synthesized and proven to form networks with different features depending on the crosslinking conditions. While networks formed from aqueous systems exhibited a reversible change in their crosslinking degree, networks generated in bulk underwent fully reversibility. The latter was then exploited for generating self-healing materials by means of a photo-induced treatment.

引用

页码：468 / 473

页数：6

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