A new hexanuclear rhenium cluster complex with six terminal acetate ligands: Synthesis, structure, and properties of K4[Re6S8(CH3COO)6]•8H2O

被引：34

作者：

Brylev, Konstantin A. ^{[1
]}

Mironov, Yuri V. ^{[1
]}

Fedorov, Vladimir E. ^{[1
]}

Kim, Sung-Jin ^{[2
]}

Pietzsch, Hans-Juergen ^{[3
]}

Stephan, Holger ^{[3
]}

Ito, Akitaka ^{[4
]}

Kitamura, Noboru ^{[4
]}

机构：

[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk 630090, Russia

[2] Ewha Womans Univ, Dept Chem & Nano Sci, Seoul 120750, South Korea

[3] Forschungszentrum Dresden Rossendorf, Inst Radiopharm, D-01314 Dresden, Germany

[4] Hokkaido Univ, Dept Chem, Grad Sch Sci, Sapporo, Hokkaido 0600810, Japan

来源：

INORGANICA CHIMICA ACTA | 2010年 / 363卷 / 11期

基金：

日本学术振兴会; 俄罗斯基础研究基金会;

关键词：

Synthesis; Cluster compounds; Rhenium; Carboxylate ligands; Luminescence; CRYSTAL-STRUCTURE; HEXARHENIUM(III) CLUSTERS; ACETIC-ACID; ORGANIC-LIGANDS; CORE; SE; MOLYBDENUM; SUBSTITUTION; LUMINESCENT; TEMPERATURE;

D O I：

10.1016/j.ica.2010.04.042

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A room-temperature reaction between [Re6S8(OH)(6)](4) and acetic acid in an aqueous solution resulted in the substitution of all terminal hydroxo groups by acetate ligands, affording a new hexanuclear anionic rhenium cluster complex [Re6S8(CH3COO)(6)](4). The complex was isolated as a potassium salt with the composition of K-4[Re6S8(CH3COO)(6)]center dot 8H(2)O (1) and characterized by X-ray single- crystal diffraction and elemental analyses, IR, H-1 NMR, UV-Vis, and luminescence spectroscopies. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：2686 / 2691

页数：6

共 41 条

[1]

Adams R.D., 1993, J CHEM SOC CHEM COMM, V4, P151, DOI 10.1007/BF00702715

[2] STRUCTURE OF 1,2-MU-ACETATO-(O,O')-1,1,1,2,2,2,3,3,3,3-DECACARBONYL-MU-HYDRIDO-TRIANGULO-TRIOSMIUM - A REDETERMINATION AND NORMAL PROBABILITY PLOT ANALYSIS [J].

ALEXIEV, VD ;

EVANS, J ;

STREET, AC ;

WEBSTER, M .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1988, 44 :1186-1189

[3] A combined stopped-flow, electrospray ionization mass spectrometry and 31P NMR study on the acetic acid-mediated fragmentation of the hydroxo-chalcogenide cluster [W3Se4(OH)3(dmpe)3]+ (dmpe=1,2-bis(dimethylphosphanyl)ethane) to yield the dinuclear [W2Se2(μ-Se)2(μ-CH3CO2)(dmpe)2]+ complex [J].

Algarra, Andres G. ;

Basallote, Manuel G. ;

Castillo, C. Esther ;

Corao, Carolina ;

Llusar, Rosa ;

Fernandez-Trujillo, M. Jesus ;

Vicent, Cristian .

DALTON TRANSACTIONS, 2006, 48 (48) :5725-5733

[4]

[Anonymous], 2015, Acta Crystallogr., V71, P3

[5] A NEW AQUEOUS CHEMISTRY OF ORGANOMETALLIC, TRINUCLEAR CLUSTER COMPOUNDS OF MOLYBDENUM [J].

BINO, A ;

COTTON, FA ;

DORI, Z .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (01) :243-244

[6] NEW CLASS OF TRINUCLEAR TUNGSTEN(IV) CLUSTER COMPOUNDS WITH W-W SINGLE BONDS [J].

BINO, A ;

COTTON, FA ;

DORI, Z ;

KOCH, S ;

KUPPERS, H ;

MILLAR, M ;

SEKUTOWSKI, JC .

INORGANIC CHEMISTRY, 1978, 17 (11) :3245-3253

[7] STRUCTURAL STUDIES OF SOME MULTIPLY BONDED DIRUTHENIUM TETRACARBOXYLATE COMPOUNDS [J].

BINO, A ;

COTTON, FA ;

FELTHOUSE, TR .

INORGANIC CHEMISTRY, 1979, 18 (09) :2599-2604

[8] [MO3(OAC)6(CH3CH2O)2(H2O)3]2+ AND OTHER NEW PRODUCTS OF REACTION BETWEEN MOLYBDENUM HEXACARBONYL AND ACETIC-ACID [J].

BINO, A ;

ARDON, M ;

MAOR, I ;

KAFTORY, M ;

DORI, Z .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (22) :7093-7095

[9] Crystal structures of the octahedral rhenium cluster compexes Cs4[Re6S8(OH)6]•6H2O and Cs4[Re6Se8(OH)6]•8H2O [J].

Brylev, K. A. ;

Mironov, Yu. V. ;

Kim, S. -J. ;

Fedorov, V. E. .

JOURNAL OF STRUCTURAL CHEMISTRY, 2007, 48 (06) :1118-1123

[10] A family of octahedral rhenium cluster complexes [Re6Q8(H2O)n(OH)6-n]n-4 (Q = S, Se; n=0-6):: Structural and pH-Dependent spectroscopic studies [J].

Brylev, Konstantin A. ;

Mironov, Yuri V. ;

Yarovoi, Spartak S. ;

Naumov, Nikolai G. ;

Fedorov, Vladimir E. ;

Kim, Sung-Jin ;

Kitamura, Noboru ;

Kuwahara, Yusuke ;

Yamada, Konatsu ;

Ishizaka, Shoji ;

Sasaki, Yoichi .

INORGANIC CHEMISTRY, 2007, 46 (18) :7414-7422

← 1 2 3 4 5 →