Electrochromic Windows with PVB Electrolytes

被引：7
作者：
Sentanin, Franciani C. [1 ]
Ponez, Lucas [1 ]
Pawlicka, Agnieszka [1 ]
机构：
[1] IQSC USP, BR-13566590 Sao Carlos, SP, Brazil
来源：
MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 2014年 / 604卷 / 01期
基金：
巴西圣保罗研究基金会;
关键词：
sol-gel; PVB electrolytes; Electrochromic windows; THIN-FILM; POLYMERIC ELECTROLYTES; SOL-GEL; GELATIN; CONDUCTIVITY; DEVICES; DNA;
D O I：
10.1080/15421406.2014.968040
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Electrochromic devices (ECDs) with WO3/PVB electrolyte/CeO2-TiO2 configuration were assembled and characterized. The ECDs revealed charge density values of 2.9 and 7.8 mC/cm(2) with a cathodic/anodic ratio of 0.9 and 1.0 for the systems containing PVB-LiClO4 and PVB-LiI electrolytes, respectively. The electrochemical stability showed a decrease of charge density, from 7.8 to 3.7 mC/cm(2) as a function of color/bleaching cycling being between 10 and 1,200(th) cycles for the ECD with PVB-LiI; and from initial 2.9 to 1.0 mC/cm(2) after 48,000 cycles for the ECD with PVB-LiClO4. Moreover, a difference in transmittance of 30% between the ECD's colored and bleached states was also observed.
引用
收藏
页码：107 / 116
页数：10
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