High energy storage performance in (Pb0.858Ba0.1Ln0.02Y0.008) (Zr0.65Sn0.3Ti0.05)O3- (Pb0.97La0.02)(Zr0.9Sn0.05Ti0.05)O3 anti-ferroelectric composite ceramics

被引：65
作者：
Zhang, Ling [1 ]
Jiang, Shenglin [1 ]
Fan, Baoyan [1 ]
Zhang, Guangzu [1 ]
机构：
[1] Huazhong Univ Sci & Technol, Sch Opt & Elect Informat, Wuhan 430074, Peoples R China
来源：
CERAMICS INTERNATIONAL | 2015年 / 41卷 / 01期
关键词：
PBLYZST-PLZST anti-ferroelectric composites; Energy storage properties; FE to AFE phase transition electric field; Anti-ferroelectric temperature stability; PLZST content; DENSITY; TITANATE;
D O I：
10.1016/j.ceramint.2014.09.041
中图分类号：
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
New anti-ferroelectric composite ceramics of (Pb0.858Ba0.1La0.02Y0.008)(Zr0.65Sn0.3Ti0.05)O-3- (Pb0.97La0.02)(Zr0.9Sn0.05Ti0.05)O-3 (PBLYZST-PLZST) have been fabricated by the conventional solid-state reaction process. The effect of PBLYZST/PLZST ratio on phase structure, dielectric, anti-ferroelectric and energy storage properties has been investigated in detail. The X-ray diffraction, field emission scanning electron microscopy and energy-dispersive spectrometry analysis illustrate that the composites are composed of tetragonal perovskite, orthorhombic perovskite and small amount of pyrochlore phases. With the increase of PLZST content, the two dielectric peaks, which link with AFE(O) to AFE(T) and AFE(T) to PE phase transition respectively, shift toward higher temperature, suggesting that the anti-ferroelectric temperature stability of the composites is enhanced. The composite ceramics with 50 wt % PLZST content possess a considerable FE-to-AFE phase transition electric field of 130 kV/cm and a high saturation polarization of 49.8 uC/cm(2) at room temperature. As a result, the maximum value of energy storage density is obtained to be 4.65 J/cm(3). (C) 2014 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
引用
收藏
页码：1139 / 1144
页数：6
相关论文
共 19 条
[11]   Large strain and high energy storage density in orthorhombic perovskite, (Pb0.97La0.02)(Zr1-x-ySnxTiy)O3 antiferroelectric thin films [J].
Mirshekarloo, Meysam Sharifzadeh ;
Yao, Kui ;
Sritharan, Thirumany .
APPLIED PHYSICS LETTERS, 2010, 97 (14)
[12]   High-Energy Density Capacitors Utilizing 0.7 BaTiO3-0.3 BiScO3 Ceramics [J].
Ogihara, Hideki ;
Randall, Clive A. ;
Trolier-McKinstry, Susan .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2009, 92 (08) :1719-1724
[13]   Pulse power capability of high energy density capacitors based on a new dielectric material [J].
Slenes, KM ;
Winsor, P ;
Scholz, T ;
Hudis, M .
IEEE TRANSACTIONS ON MAGNETICS, 2001, 37 (01) :324-327
[14]   Influence of Pb(In1/2Nb1/2)O3 on the Phase Transitions, Electrical, and Thermal Properties of a PbZrO3 Ceramic [J].
Sukkha, Usa ;
Muanghlua, Rangson ;
Niemcharoen, Surasak ;
Boonchom, Banjong ;
Vittayakorn, Naratip .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2011, 94 (10) :3397-3404
[15]   Composition and shape control of single-crystalline Ba1-xSrxTiO3 (x=0-1) nanocrystals via a solvothermal route [J].
Wei, Xiao ;
Xu, Gang ;
Ren, Zhaohui ;
Wang, Yonggang ;
Shen, Ge ;
Han, Gaorong .
JOURNAL OF CRYSTAL GROWTH, 2008, 310 (18) :4132-4137
[16]   Mechanical vs. electrical failure mechanisms in high voltage, high energy density multillayer ceramic capacitors [J].
Young, Amanda Lynn ;
Hilmas, Gregory E. ;
Zhang, Shi C. ;
Schwartz, Robert W. .
JOURNAL OF MATERIALS SCIENCE, 2007, 42 (14) :5613-5619
[17]   Charge-Discharge Properties of an Antiferroelectric Ceramics Capacitor Under Different Electric Fields [J].
Zhang, Hongling ;
Chen, Xuefeng ;
Cao, Fei ;
Wang, Genshui ;
Dong, Xianlin ;
Hu, Zhiying ;
Du, Tao .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2010, 93 (12) :4015-4017
[18]   Y doping and grain size co-effects on the electrical energy storage performance of (Pb0.87Ba0.1La0.02) (Zr0.65Sn0.3Ti0.05)O3 anti-ferroelectric ceramics [J].
Zhang, Ling ;
Jiang, Shenglin ;
Zeng, Yike ;
Fu, Ming ;
Han, Kuo ;
Li, Qi ;
Wang, Qing ;
Zhang, Guangzu .
CERAMICS INTERNATIONAL, 2014, 40 (04) :5455-5460
[19]   Improved Energy Storage Density in Barium Strontium Titanate by Addition of BaO-SiO2-B2O3 Glass [J].
Zhang, Qingmeng ;
Wang, Lei ;
Luo, Jun ;
Tang, Qun ;
Du, Jun .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2009, 92 (08) :1871-1873
12