Highly-efficient fabrication of nanoscrolls from functionalized graphene oxide by Langmuir-Blodgett method

被引：89
作者：
Gao, Yan [1 ,2 ,3 ]
Chen, Xiaoqiang [2 ]
Xu, Hao [1 ,2 ]
Zou, Yunlong [2 ]
Gu, Renpeng [2 ]
Xu, Mingsheng [2 ]
Jen, Alex K. -Y. [3 ]
Chen, Hongzheng [1 ,2 ]
机构：
[1] Zhejiang Univ, State Key Lab Silicon Mat, Zhejiang California Int Nanosyst Inst, Hangzhou 310027, Peoples R China
[2] Zhejiang Univ, MOE Key Lab Macromol Synth & Functionalizat, Dept Polymer Sci & Engn, Hangzhou 310027, Peoples R China
[3] Univ Washington, Dept Mat Sci & Engn, Seattle, WA 98195 USA
来源：
CARBON | 2010年 / 48卷 / 15期
基金：
中国国家自然科学基金;
关键词：
CARBON NANOSCROLLS; GRAPHITE OXIDE; NANOWIRES; NANOTUBES; SURFACE; EXFOLIATION; NANOSHEETS; REDUCTION; GROWTH; FILMS;
D O I：
10.1016/j.carbon.2010.08.007
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
We report a Langmuir-Blodgett (LB) approach for highly-efficient fabrication of nanoscrolls from functionalized graphene oxide single sheets. Transmission electron microscope study reveals that the scroll has a tubular structure without caps at its ends. The scrolls align parallel to the moving barriers of the LB equipment and exhibit a loose-dense pattern during the LB compression process. We find that specific solvents can unwind the scrolled structures. Electrical characterization of the well-aligned scrolls was also performed. The method demonstrated here opens up a new avenue for high-yield fabrication of carbon nanoscrolls using functionalized graphene oxide as the building blocks. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码：4475 / 4482
页数：8
相关论文
共 41 条
  • [1] Enzyme-coated carbon nanotubes as single-molecule biosensors
    Besteman, K
    Lee, JO
    Wiertz, FGM
    Heering, HA
    Dekker, C
    [J]. NANO LETTERS, 2003, 3 (06) : 727 - 730
  • [2] Hydrogen storage in carbon nanoscrolls: An atomistic molecular dynamics study
    Braga, S. F.
    Coluci, V. R.
    Baughman, R. H.
    Galvao, D. S.
    [J]. CHEMICAL PHYSICS LETTERS, 2007, 441 (1-3) : 78 - 82
  • [3] Structure and dynamics of carbon nanoscrolls
    Braga, SF
    Coluci, VR
    Legoas, SB
    Giro, R
    Galvao, DS
    Baughman, RH
    [J]. NANO LETTERS, 2004, 4 (05) : 881 - 884
  • [4] Fabrication of rare-earth biphthalocyanine encapsulated by carbon nanotubes using a capillary filling method
    Cao, L
    Chen, HZ
    Li, HY
    Zhou, HB
    Sun, JZ
    Zhang, XB
    Wang, M
    [J]. CHEMISTRY OF MATERIALS, 2003, 15 (17) : 3247 - 3249
  • [5] Raman fingerprint of charged impurities in graphene
    Casiraghi, C.
    Pisana, S.
    Novoselov, K. S.
    Geim, A. K.
    Ferrari, A. C.
    [J]. APPLIED PHYSICS LETTERS, 2007, 91 (23)
  • [6] Chiral carbon nanoscrolls with a polygonal cross-section
    Chuvilin, Andrey L.
    Kuznetsov, Vladimir L.
    Obraztsov, Alexander N.
    [J]. CARBON, 2009, 47 (13) : 3099 - 3105
  • [7] Langmuir-Blodgett Assembly of Graphite Oxide Single Layers
    Cote, Laura J.
    Kim, Franklin
    Huang, Jiaxing
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (03) : 1043 - 1049
  • [8] High-performance thin-film transistors using semiconductor nanowires and nanoribbons
    Duan, XF
    Niu, CM
    Sahi, V
    Chen, J
    Parce, JW
    Empedocles, S
    Goldman, JL
    [J]. NATURE, 2003, 425 (6955) : 274 - 278
  • [9] Functionalization of carbon nanotubes with amphiphilic molecules and their Langmuir-Blodgett films
    Feng, L
    Li, HJ
    Li, FY
    Shi, ZJ
    Gu, ZN
    [J]. CARBON, 2003, 41 (12) : 2385 - 2391
  • [10] Raman spectrum of graphene and graphene layers
    Ferrari, A. C.
    Meyer, J. C.
    Scardaci, V.
    Casiraghi, C.
    Lazzeri, M.
    Mauri, F.
    Piscanec, S.
    Jiang, D.
    Novoselov, K. S.
    Roth, S.
    Geim, A. K.
    [J]. PHYSICAL REVIEW LETTERS, 2006, 97 (18)
12345