Cuprophilic and π-stacking interactions in the formation of supramolecular stacks from dicoordinate organocopper complexes

被引：70
|
作者：
Sundararaman, A
Zakharov, LN
Rheingold, AL
Jäkle, F
机构：
[1] Rutgers State Univ, Dept Chem, Newark, NJ 07102 USA
[2] Univ Calif San Diego, Dept Chem & Biochem, La Jolla, CA 92093 USA
来源：
CHEMICAL COMMUNICATIONS | 2005年 / 13期
关键词：
D O I：
10.1039/b417532h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The unsupported organocopper pyridine complexes C6F5Cu(py) (2) and [C6F5Cu](2)(4,4'-bipy) ( 3) form supramolecular structures that are unprecedented in organocopper chemistry; one-dimensional chains of copper atoms with Cu center dot center dot center dot Cu distances of 2.8924( 3) angstrom in the blue-luminescent complex 2 are likely associated with cuprophilic interactions, whereas multiple perfluoroarene-arene interactions dominate in the supramolecular assembly of 3.
引用
收藏
页码：1708 / 1710
页数：3
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