Cuprophilic and π-stacking interactions in the formation of supramolecular stacks from dicoordinate organocopper complexes

被引：71

作者：

Sundararaman, A

Zakharov, LN

Rheingold, AL

Jäkle, F

机构：

[1] Rutgers State Univ, Dept Chem, Newark, NJ 07102 USA

[2] Univ Calif San Diego, Dept Chem & Biochem, La Jolla, CA 92093 USA

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 13期

关键词：

D O I：

10.1039/b417532h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The unsupported organocopper pyridine complexes C6F5Cu(py) (2) and [C6F5Cu](2)(4,4'-bipy) ( 3) form supramolecular structures that are unprecedented in organocopper chemistry; one-dimensional chains of copper atoms with Cu center dot center dot center dot Cu distances of 2.8924( 3) angstrom in the blue-luminescent complex 2 are likely associated with cuprophilic interactions, whereas multiple perfluoroarene-arene interactions dominate in the supramolecular assembly of 3.

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页码：1708 / 1710

页数：3

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