3-(7,8,13,14-Tetrahydrodibenzo[a,i]phenanthridin-5-yl)benzene-1,2-diol

被引:0
|
作者
Karthikeyan, N. S. [2 ]
Ramachandran, G. [2 ]
Sathiyanarayanan, K. [2 ]
Raghavaiah, P. [3 ]
Rathore, R. S. [1 ]
机构
[1] Univ Hyderabad, Sch Life Sci, Dept Biotechnol, Bioinformat Infrastruct Facil, Hyderabad 500046, Andhra Pradesh, India
[2] VIT Univ, Sch Adv Sci, Div Chem, Vellore 632014, Tamil Nadu, India
[3] Univ Hyderabad, Sch Chem, Hyderabad 500046, Andhra Pradesh, India
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷
关键词
D O I
10.1107/S1600536810023688
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, C(27)H(21)NO(2), the half-chair conformation of the alicyclic rings gives rise to a slightly folded structure of the central tricyclic tetrahydrophenanthridine unit. Tandem intramolecular O-H center dot center dot center dot N and O-H center dot center dot center dot O hydrogen bonds give rise to adjacent S(6) and S(5) rings, respectively, which dictate the conformation of the 5-aryl substituent. In the crystal structure, an intermolecular C-H center dot center dot center dot O contact generates chains parallel to [101]. Short O-H center dot center dot center dot pi and C-H center dot center dot center dot pi contacts are also observed.
引用
收藏
页码:O1753 / U141
页数:13
相关论文
共 50 条
  • [1] 3-[3-(trifluoromethyl)phenyliminomethyl]benzene-1,2-diol
    Shuja, Shaukat
    Ali, Saqib
    Meetsma, Auke
    Broker, Grant A.
    Tiekink, Edward R. T.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : O1781 - O1782
  • [2] 3-(4-Bromophenyliminomethyl)benzene-1,2-diol
    Shuja, Shaukat
    Ali, Saqib
    Shahzadi, Saira
    Labat, Gael
    Stoeckli-Evans, Helen
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : O4789 - O4790
  • [3] Molecular Structure of (E)-3-[(2bromophenylimino)methyl] benzene-1,2-diol, (I) and (E)-3-[(2-(trifluoromethyl)phenylimino)methyl]benzene-1,2-diol, (II)
    Temel, Ersin
    Buyukgungor, Orhan
    Odabasoglu, Mustafa
    Albayrak, Cigdem
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2007, 63 : S232 - S232
  • [4] (E)-3-[(2-bromophenyl)iminomethyl]-benzene-1,2-diol
    Temel, Ersin
    Albayrak, Cigdem
    Odabasoglu, Mustafa
    Buyukgungor, Orhan
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : o1319 - o1320
  • [5] (E)-3-[(2-Fluorophenylimino)methyl]-benzene-1,2-diol
    Temel, Ersin
    Albayrak, Cigdem
    Odabasoglu, Mustafa
    Bueyuekguengoer, Orhan
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : O2642 - U1265
  • [6] (E)-3-[2-(trifluoromethyl)phenyliminomethyl]-benzene-1,2-diol
    Temel, Ersin
    Albayrak, Cigdem
    Odabasoglu, Mustafa
    Buyukgungor, Orhan
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : O374 - O376
  • [7] 3-[(E)-(4-Ethylphenyl)iminomethyl]benzene-1,2-diol
    Kelesoglu, Zeynep
    Buyukgungor, Orhan
    Albayrak, Cigdem
    Odabasoglu, Mustafa
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : O2055 - U4670
  • [8] (E)-3-[(4-Butylphenyl)iminomethyl]benzene-1,2-diol
    Kelesoglu, Zeynep
    Buyukgungor, Orhan
    Albayrak, Cigdem
    Odabasoglu, Mustafa
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : O2022 - U4401
  • [9] (Z)-3-({[3-Methoxy-5-(trifluoromethyl)phenyl]imino}methyl)benzene-1,2-diol
    Kanmazalp, Sibel Demir
    Dogan, Onur Erman
    Dege, Necmi
    Agar, Erbil
    Bulbul, Hakan
    Golenya, Irina A.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2019, 75 : 470 - +
  • [10] Dual Behavior of 2-Tetralone: A New Approach for the Synthesis of 5-Aryl-7,8,13,14-tetrahydrodibenzo[a,i]phenanthridine
    Sathiyanarayanan, Kulathu Iyer
    Karthikeyan, Natesan Sundaramurthy
    Aravindan, Paduthapillai Gopal
    Shanthi, Seenan
    Rathore, Ravindranath S.
    Lee, Chang Woo
    JOURNAL OF HETEROCYCLIC CHEMISTRY, 2009, 46 (06) : 1142 - 1144