Ligand-free ZnS nanoparticles: as easy and green as it gets

被引:10
作者
Dengo, Nicola [1 ,2 ]
Faresin, Andrea [1 ,2 ]
Carofiglio, Tommaso [1 ,2 ]
Maggini, Michele [1 ,2 ]
Wu, Longfei [3 ]
Hofmann, Jan P. [3 ]
Hensen, Emiel J. M. [3 ]
Dolcet, Paolo [1 ,2 ,4 ]
Gross, Silvia [1 ,2 ]
机构
[1] Univ Padua, Dipartimento Sci Chim, Via Marzolo 1, I-35131 Padua, Italy
[2] INSTM UdR, Via Marzolo 1, I-35131 Padua, Italy
[3] Eindhoven Univ Technol, Dept Chem Engn & Chem, Lab Inorgan Mat & Catalysis, POB 513, NL-5600 MB Eindhoven, Netherlands
[4] Karlsruher Inst Technol KIT, Inst Tech Chem & Polymerchem ITCP, Engesserstr 20, D-76131 Karlsruhe, Germany
关键词
GROWTH; NUCLEATION; PHOTOCATALYSTS; PH;
D O I
10.1039/d0cc01901a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The controlled nucleation and crystallization of small pure sphalerite ZnS nanoparticles was achieved under batch and continuous flow conditions at low temperature, in water and without the use of any stabilizing ligand. The obtained nanoparticles displayed a narrow size distribution and high specific surface area. Moreover, the synthesis was suitable to directly obtain stable water-based suspensions and the products were found to be active photocatalysts for the hydrogen evolution reaction.
引用
收藏
页码:8707 / 8710
页数:4
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