Electromotive Force Measurements in Liquid Li-Si Alloys

被引：10

作者：

Fima, Przemyslaw ^{[1
]}

Debski, Adam ^{[1
]}

Gasior, Wladyslaw ^{[1
]}

机构：

[1] Polish Acad Sci, Inst Met & Mat Sci, PL-30059 Krakow, Poland

来源：

JOURNAL OF PHASE EQUILIBRIA AND DIFFUSION | 2012年 / 33卷 / 05期

关键词：

activity; electromotive force (emf); liquid; Li-Si system; LITHIUM-SILICON SYSTEM; THERMODYNAMIC PROPERTIES; EMF;

D O I：

10.1007/s11669-012-0072-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Electromotive force measurements on the Li-Si system were initiated by the concentration cell method with an (LiCl-LiF)(eut) electrolyte and the (Bi,Li3Bi(l) + Li3Bi(s)) two phase alloy as a reference electrode. The measurements are carried out in the temperature range between 880 and 1020 K for liquid alloys containing 0.57, 0.61, 0.815, and 0.85 mole fractions of Li. The activities of Li in liquid Li-Si alloys determined in this work are compared with the activities calculated from the set of thermodynamic parameters optimized by Braga et al. Present results are in reasonable agreement with calculated data.

引用

页码：352 / 356

页数：5

共 19 条

[1]

[Anonymous], 1994, ARCH METALL

[2] Thermodynamic assessment of the Li-Si system [J].

Braga, MH ;

Malheiros, LF ;

Ansara, I .

JOURNAL OF PHASE EQUILIBRIA, 1995, 16 (04) :324-330

[3]

Gasior W, 1999, ARCH METALL, V44, P83

[4] Thermodynamic studies and the phase diagram of the Li-Sn system [J].

Gasior, W ;

Moser, Z ;

Zakulski, W .

JOURNAL OF NON-CRYSTALLINE SOLIDS, 1996, 205 :379-382

[5] Thermodynamic study of liquid lithium-lead alloys using the EMF method [J].

Gasior, W ;

Moser, Z .

JOURNAL OF NUCLEAR MATERIALS, 2001, 294 (1-2) :77-83

[6]

Gasior W., 1991, THESIS KRAKOW

[7] Thermally activated ("thermal") battery technology - Part IV. Anode materials [J].

Guidotti, Ronald A. ;

Masset, Patrick J. .

JOURNAL OF POWER SOURCES, 2008, 183 (01) :388-398

[8]

Karnowsky M.M., 1984, SAND840741 SAND NAT

[9] SOLID LITHIUM-SILICON ELECTRODE [J].

LAI, SC .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1976, 123 (08) :1196-1197

[10] CALORIMETRIC AND EMF STUDIES ON LIQUID LI-SN ALLOYS [J].

MOSER, Z ;

GASIOR, W ;

SOMMER, F ;

SCHWITZGEBEL, G ;

PREDEL, B .

METALLURGICAL TRANSACTIONS B-PROCESS METALLURGY, 1986, 17 (04) :791-796

← 1 2 →