Hydrothermal synthesis of rutile TiO2 nanoflowers using Bronsted Acidic Ionic Liquid [BAIL]: Synthesis, characterization and growth mechanism

被引:68
作者
Mali, Sawanta S. [1 ]
Betty, Chirayath A. [2 ]
Bhosale, Popatrao N. [3 ]
Devan, Rupesh S. [4 ]
Ma, Yuan-Ron [4 ]
Kolekar, Sanjay S. [1 ]
Patil, Pramod S. [1 ]
机构
[1] Shivaji Univ, Dept Phys, Thin Film Mat Lab, Kolhapur 416004, Maharashtra, India
[2] Bhabha Atom Res Ctr, Div Chem, Trombay Mumbai 85, India
[3] Shivaji Univ, Dept Chem, Mat Res Lab, Kolhapur 416004, Maharashtra, India
[4] Natl Dong Hwa Univ, Dept Phys, Hualien 97401, Taiwan
关键词
NANOSTRUCTURES; MICROSPHERES; NANOCRYSTALS; TEMPLATE; NANORODS; SOLVENT; FILMS;
D O I
10.1039/c2ce06476f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Herein we report a facile method to synthesize rutile TiO2 nano-flowers (TNF) comprising a bunch of aligned nanorods with uniform size and shape via a hydrothermal method in Bronsted Acidic Ionic Liquid [BAIL] room temperature ionic liquid (RTIL). This method has some advantages: the process is simple and single step; the reaction can be performed under low temperature. The TNFs are highly crystalline and free of aggregation.
引用
收藏
页码:1920 / 1924
页数:5
相关论文
共 30 条
[21]   The selective fabrication of large-area highly ordered TiO2 nanorod and nanotube arrays on conductive transparent substrates via sol-gel electrophoresis [J].
Ren, X. ;
Gershon, T. ;
Iza, D. C. ;
Munoz-Rojas, D. ;
Musselman, K. ;
MacManus-Driscoll, J. L. .
NANOTECHNOLOGY, 2009, 20 (36)
[22]  
Sun CH, 2008, CHEM COMMUN, P3293, DOI 10.1039/b805072d
[23]  
Swamy V., 2006, APPL PHYS LETT
[24]   Monodisperse rutile TiO2 nanorod-based microspheres with various diameters: hydrothermal synthesis, formation mechanism and diameter- and crystallinity-dependent photocatalytic properties [J].
Tian, Sha ;
Yang, Heqing ;
Cui, Meng ;
Shi, Ruiyu ;
Zhao, Hua ;
Wang, Xuewen ;
Wang, Xinyue ;
Zhang, Lina .
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2011, 104 (01) :149-158
[25]   Hydrothermal synthesis of ordered single-crystalline rutile TiO2 nanorod arrays on different substrates [J].
Wang, Hong-En ;
Chen, Zhenhua ;
Leung, Yu Hang ;
Luan, Chunyan ;
Liu, Chaoping ;
Tang, Yongbing ;
Yan, Ce ;
Zhang, Wenjun ;
Zapien, Juan Antonio ;
Bello, Igor ;
Lee, Shuit-Tong .
APPLIED PHYSICS LETTERS, 2010, 96 (26)
[26]   Room-temperature ionic liquids. Solvents for synthesis and catalysis [J].
Welton, T .
CHEMICAL REVIEWS, 1999, 99 (08) :2071-2083
[27]   Ionic liquid assisted preparation of nanostructured TiO2 particles [J].
Yoo, K ;
Choi, H ;
Dionysiou, DD .
CHEMICAL COMMUNICATIONS, 2004, (17) :2000-2001
[28]   Synthesis of anatase nanostructured TiO2 particles at low temperature using ionic liquid for photocatalysis [J].
Yoo, KS ;
Choi, H ;
Dionysiou, DD .
CATALYSIS COMMUNICATIONS, 2005, 6 (04) :259-262
[29]   Ionic liquid of [Bmim]+ Cl- for the preparation of hierarchical nanostructured rutile titania [J].
Yu, Ningya ;
Gong, Liming ;
Song, Huijuan ;
Liu, Yong ;
Yin, Donghong .
JOURNAL OF SOLID STATE CHEMISTRY, 2007, 180 (02) :799-803
[30]   Synthesis of very small TiO2 nanocrystals in a room-temperature ionic liquid and their self-assembly toward mesoporous spherical aggregates [J].
Zhou, Y ;
Antonietti, M .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (49) :14960-14961