On cationic mobility in Nasicon phosphates LiTi2(PO4)3 and Li0.9Ti1.9Nb0.1(PO4)3

被引：30

作者：

Pinus, I. Yu ^{[1
]}

Khoroshilov, A. V. ^{[1
]}

Gavrichev, K. S. ^{[1
]}

Tarasov, V. P. ^{[1
]}

Yaroslavtsev, A. B. ^{[1
]}

机构：

[1] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 119991, Russia

来源：

SOLID STATE IONICS | 2012年 / 212卷

关键词：

Nasicon; Lithium mobility; DSC; Li-7; NMR; Phase transition; LITHIUM MOBILITY; IMPEDANCE SPECTROSCOPY; NEUTRON-DIFFRACTION; PHASE-TRANSITIONS; LI-ION; NMR; SC; NB; LI1+/-XZR2-XMX(PO4)(3); ELECTROLYTES;

D O I：

10.1016/j.ssi.2012.01.035

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A systematic examination of LiTi2(PO4)(3) and Li0.9Ti1.9Nb0.1(PO4)(3) phosphates with Nasicon structure was carried out in order to investigate "order-disorder" phase transitions. The structural features of aliovalent doped Li0.9Ti1.9Nb0.1(PO4)(3) are considered in comparison with initial LiTi2(PO4)(3). Explanations of the thermal behavior of samples are proposed based on NMR Li-7, Nb-93 data, X-ray powder diffraction. DSC and impedance spectroscopy. (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：112 / 116

页数：5

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