π-Conjugated N-heterocyclic compounds:: correlation of computational and electrochemical data

被引：15

作者：

Al-Anber, M ^{[1
]}

Vartsadze, S

Holze, R

Lang, H

Thiel, WR

机构：

[1] Mutah Univ, Fac Sci, Dept Chem Sci, Al Karak, Jordan

[2] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119992, Russia

[3] Tech Univ Chemnitz, Fac Nat Wissensch, Inst Chem, D-09111 Chemnitz, Germany

[4] Univ Kaiserslautern, Fachbereich Chem, D-67663 Kaiserslautern, Germany

来源：

DALTON TRANSACTIONS | 2005年 / 22期

关键词：

D O I：

10.1039/b508314a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Electrochemical reduction potentials of a broad selection of nitrogen-containing molecules suitable as bridging (dipodal and tripodal) ligands in coordination and organometallic chemistry are reported and compared with results of semiempirical calculations. Trends of electrode potentials observed experimentally agree with respective calculated data, deviations can be explained by invoking peculiarities of the involved molecular orbitals and ligand-electrode surface interactions.

引用

收藏

页码：3632 / 3637

页数：6

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