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Synthesis and characterization of new planar butterfly-shaped fused oligothiophenes
被引:18
作者:
Wang, Jing
[1
]
Xu, Huan
[1
]
Li, Bin
[1
]
Cao, Xiao-Ping
[1
]
Zhang, Hao-Li
[1
]
机构:
[1] Lanzhou Univ, Coll Chem & Chem Engn, SKLAOC, Lanzhou 730000, Peoples R China
来源:
基金:
中国国家自然科学基金;
关键词:
Oligothiophene;
Organic semiconductor;
Fused-ring systems;
Air-stable;
THIN-FILM TRANSISTORS;
HIGH-PERFORMANCE;
PENTACENE;
SEMICONDUCTORS;
D O I:
10.1016/j.tet.2011.11.061
中图分类号:
O62 [有机化学];
学科分类号:
070303 ;
081704 ;
摘要:
A simple oxidative cyclization reaction was used to construct new seven-ring-fused butterfly-shaped oligothiophene backbone: dibenzothieno[1,2-b:4,3-b':6,7-b '':9,8-b''']tetrathiophene. The new materials show high stability and strong solid state fluorescence. X-ray crystallography results reveal that they exist in 2-D stacked structures in their crystals. (C) 2011 Elsevier Ltd. All rights reserved.
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页码:1192 / 1197
页数:6
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