The effects of oxygen concentration on ultraviolet luminescence of ZnO films by sol-gel technology and annealing

被引:24
作者
Hsieh, P. T. [1 ]
Chen, Y. C. [2 ]
Lee, M. S. [3 ]
Kao, K. S. [4 ]
Kao, M. C. [5 ]
Houng, M. P. [6 ]
机构
[1] Natl Cheng Kung Univ, Ctr Micro Nano Sci & Technol, Tainan 886701, Taiwan
[2] Natl Sun Yat Sen Univ, Dept Elect Engn, Kaohsiung 80424, Taiwan
[3] Natl Kaohsiung Univ Appl Sci, Dept Elect Engn, Kaohsiung, Taiwan
[4] Shu Te Univ, Dept Comp & Commun, Kaohsiung, Taiwan
[5] Hsiuping Inst Technol, Dept Elect Engn, Taichung, Taiwan
[6] Natl Cheng Kung Univ, Inst Microelect, Tainan 70101, Taiwan
关键词
ZnO; sol-gel processes; annealing; UV;
D O I
10.1007/s10971-008-1747-7
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
ZnO thin films were successfully deposited on SiO2/Si substrate using the sol-gel technique and annealed in various annealing atmospheres at 900 C by rapid thermal annealing (RTA). X-ray diffraction revealed the (002) texture of ZnO thin films. Scanning electron microscopy (SEM) and atomic force microscopy (AFM) showed that the grains of the ZnO thin film were enlarged and its surface was smoothed upon annealing in oxygen. PL measurement revealed two ultraviolet (UV) luminescence bands at 375 and 380 nm. The intensity of the emission peak at 380 nm became stronger as the concentration of oxygen in the annealing atmosphere increased. The X-ray photoelectron spectrum (XPS) demonstrated that a more stoichiometric ZnO thin film was obtained upon annealing in oxygen and more excitons were generated from the radiative recombination carriers consistently. Additionally, the UV intensity increased with the thickness of ZnO thin film.
引用
收藏
页码:1 / 6
页数:6
相关论文
共 26 条
[1]   Strong ultraviolet and green emissions at room temperature from annealed ZnO thin films [J].
Agyeman, O ;
Xu, CN ;
Shi, WS ;
Zheng, XG ;
Suzuki, M .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 2002, 41 (2A) :666-669
[2]   LUMINESCENCE OF HETEROEPITAXIAL ZINC-OXIDE [J].
BETHKE, S ;
PAN, H ;
WESSELS, BW .
APPLIED PHYSICS LETTERS, 1988, 52 (02) :138-140
[3]   Transparent ZnO thin-film transistor fabricated by rf magnetron sputtering [J].
Carcia, PF ;
McLean, RS ;
Reilly, MH ;
Nunes, G .
APPLIED PHYSICS LETTERS, 2003, 82 (07) :1117-1119
[4]   Influence of post-annealing treatment on the structure properties of ZnO films [J].
Fang, ZB ;
Yan, ZJ ;
Tan, YS ;
Liu, XQ ;
Wang, YY .
APPLIED SURFACE SCIENCE, 2005, 241 (3-4) :303-308
[5]   Effect of thermal annealing treatment on structural, electrical and optical properties of transparent sol-gel ZnO thin films [J].
Ghosh, R ;
Paul, GK ;
Basak, D .
MATERIALS RESEARCH BULLETIN, 2005, 40 (11) :1905-1914
[6]   Effect of thermal annealing on the optical and electronic properties of ZnO thin films grown on p-Si substrates [J].
Han, WG ;
Kang, SG ;
Kim, TW ;
Kim, DW ;
Cho, WJ .
APPLIED SURFACE SCIENCE, 2005, 245 (1-4) :384-390
[7]   ZnO-based transparent thin-film transistors [J].
Hoffman, RL ;
Norris, BJ ;
Wager, JF .
APPLIED PHYSICS LETTERS, 2003, 82 (05) :733-735
[8]   The ultraviolet emission mechanism of ZnO thin film fabricated by sol-gel technology [J].
Hsieh, P. T. ;
Chen, Y. C. ;
Kao, K. S. ;
Lee, M. S. ;
Cheng, C. C. .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2007, 27 (13-15) :3815-3818
[9]   TEXTURED ALUMINUM-DOPED ZINC-OXIDE THIN-FILMS FROM ATMOSPHERIC-PRESSURE CHEMICAL-VAPOR DEPOSITION [J].
HU, JH ;
GORDON, RG .
JOURNAL OF APPLIED PHYSICS, 1992, 71 (02) :880-890
[10]   Epitaxial growth of Al-doped ZnO thin films grown by pulsed laser deposition [J].
Kim, H ;
Horwitz, JS ;
Qadri, SB ;
Chrisey, DB .
THIN SOLID FILMS, 2002, 420 :107-111