Metal-Free Synthesis of Polysubstituted Pyrroles by (Diacetoxyiodo)Benzene-Mediated Cascade Reaction of 3-Alkynyl Amines

被引：18

作者：

Mo, Dong-Liang ^{[1
]}

Ding, Chang-Hua ^{[1
]}

Dai, Li-Xin ^{[1
]}

Hou, Xue-Long ^{[1
,2
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

[2] Chinese Acad Sci, Shanghai Inst Organ Chem, Shanghai Hong Kong Joint Lab Chem Synth, Shanghai 200032, Peoples R China

来源：

CHEMISTRY-AN ASIAN JOURNAL | 2011年 / 6卷 / 12期

基金：

中国国家自然科学基金;

关键词：

amines; cascade reaction; hypervalent compounds; pyrrole; regioselectivity; REGIOSELECTIVE SYNTHESIS; EFFICIENT SYNTHESIS; SUBSTITUTED PYRROLES; ONE-POT; CATALYZED SYNTHESIS; TERMINAL ALKYNES; CYCLIZATION; CYCLOADDITION; IMINES; ACID;

D O I：

10.1002/asia.201100474

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Free metal jacket: A regioselective metal-free synthesis of polysubstituted pyrroles has been developed through a (diacetoxyiodo)benzene-mediated cascade reaction of alkynyl amines in moderate to good yield (see scheme). © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：3200 / 3204

页数：5