[Fe2{SeC6H2-2,4,6-Ph3}2{N(SiMe3)2}2] and [Fe2{SeC6H2-2,4,6-Ph3}4], the first three-coordinate selenolatoiron complexes

被引：0

作者：

Hauptmann, R ^{[1
]}

Kliss, R ^{[1
]}

Henkel, G ^{[1
]}

机构：

[1] Univ Duisburg Gesamthsch, Inst Synth Chem, D-47048 Duisburg, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1999年 / 38卷 / 03期

关键词：

iron; nitrogen; nitrogenase; selenium;

D O I：

10.1002/(SICI)1521-3773(19990201)38:3<377::AID-ANIE377>3.0.CO;2-5

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In a controlled manner, half or all the bis(trimethylsilyl)amido ligands of 1 can be replaced by selenolato ligands, resulting in the first selenolatoiron complexes 2 and 3 with three-coordinate iron centers. They are stabilized by secondary metal-framework bonds (here metal-carbon) and could, since they are coordinatively unsaturated, possibly serve as model compounds of the FeMo cofactor of nitrogenases.

引用

页码：377 / 379

页数：3

共 29 条

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