Adsorption of Cu2+ Ions from Aqueous Solutions on Nano-Titanate Engelhard Titanosilicate-2 (ETS-2)

被引:0
作者
Rezaei, Sabereh [1 ]
Kuznicki, Steven M. [1 ]
机构
[1] Univ Alberta, Dept Chem & Mat Engn, Edmonton, AB T6G 2V4, Canada
关键词
Adsorption; Heavy Metal Removal; Copper; Nano-Titanate ETS-2; Water Treatment; HEAVY-METAL IONS; CU(II) IONS; WASTE-WATER; EXCHANGED NANOTITANATE; H2S ADSORPTION; NI(II) IONS; REMOVAL; COPPER; ZN(II); CO(II);
D O I
10.1166/jnn.2018.14698
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Adsorption of Cu2+ ions from aqueous solutions is an increasingly important problem. Nano-titanate ETS-2 (Engelhard Titanosilicate-2) was studied for Cu2+ removal from aqueous solutions through the batch technique at room temperature. Structural and chemical properties of both ETS-2 sorbent and aqueous solution were studied by different characterization tests such as Thermogravimetric Analysis, Energy Dispersive X-ray spectroscopy, X-ray Photoelectron Spectroscopy and Inductively Coupled Plasma measuremen. Copper adsorption capacity was found to increase upon raising the contact time or the pH of the solution. The maximum uptake of Cu2+ (99.9%) by ETS-2 occurred at pH of 6.7 and 30 min of contact time. The Cu2+ removal capacity of ETS-2 was found to be 53.58 mg/g at pH = 5.16, which improved to 54.02 mg/g, when rising the contact time to 90 min. Chemical properties of ETS-2 indicated that ETS-2 surface possessed sodium exchange sites making it a favourable sorbent for metal exchange.
引用
收藏
页码:3619 / 3623
页数:5
相关论文
共 37 条
[1]   Adsorptive Removal and Recovery of U(VI), Cu(II), Zn(II), and Co(II) from Water and Industry Effluents [J].
Anirudhan, T. S. ;
Radhakrishnan, P. G. .
BIOREMEDIATION JOURNAL, 2011, 15 (01) :39-56
[2]   Adsorptive Accumulation of Cd(II), Co(II), Cu(II), Pb(II) and Ni(II) Ions from Water onto Kaolinite: Influence of Acid Activation [J].
Bhattacharyya, Krishna G. ;
Sen Gupta, Susmita .
ADSORPTION SCIENCE & TECHNOLOGY, 2009, 27 (01) :47-68
[3]   Applications of Nanotechnology in Wastewater Treatment-A Review [J].
Bora, Tanujjal ;
Dutta, Joydeep .
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2014, 14 (01) :613-626
[4]   Adsorptive removal of Co(II), Ni(II), and Cu(II) ions from aqueous media using chemically modified sporopollenin of Lycopodium clavatum as novel biosorbent [J].
Cimen, Aysel ;
Bilgic, Ali ;
Kursunlu, Ahmed Nuri ;
Gubbuk, Ilkay Hilal ;
Ucan, Halil Ismet .
DESALINATION AND WATER TREATMENT, 2014, 52 (25-27) :4837-4847
[5]   Adsorptive removal of Cu(II) and Ni(II) ions from aqueous media by chemical immobilization of three different aldehydes [J].
Dumrul, Hakan ;
Kursunlu, Ahmed Nuni ;
Kocyigit, Ozcan ;
Guler, Ersin ;
Ertul, Seref .
DESALINATION, 2011, 271 (1-3) :92-99
[6]   Effect of moisture on H2S adsorption by copper impregnated activated carbon [J].
Huang, Chen-Chia ;
Chen, Chien-Hung ;
Chu, Shu-Min .
JOURNAL OF HAZARDOUS MATERIALS, 2006, 136 (03) :866-873
[7]   Spherical polystyrene-supported chitosan thin film of fast kinetics and high capacity for copper removal [J].
Jiang, Wei ;
Chen, Xubin ;
Pan, Bingcai ;
Zhang, Quanxing ;
Teng, Long ;
Chen, Yufan ;
Liu, Lu .
JOURNAL OF HAZARDOUS MATERIALS, 2014, 276 :295-301
[8]   Comparison of Amberlite IR 120 and dolomite's performances for removal of heavy metals [J].
Kocaoba, Sevgi .
JOURNAL OF HAZARDOUS MATERIALS, 2007, 147 (1-2) :488-496
[9]   Highly Luminescent Mesoporous Zn2TiO4:Eu3+ Material with Excellent Sensing and Removal Abilities for Heavy-Metal Ions [J].
Li, Jianmin ;
Wu, Bin ;
Zhang, Qinghong ;
Wang, Hongzhi ;
Li, Yaogang .
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2016, 16 (09) :9568-9574
[10]   Adsorption behavior of Cu(II) onto titanate nanofibers prepared by alkali treatment [J].
Li, Nian ;
Zhang, Lide ;
Chen, Yongzhou ;
Tian, Yue ;
Wang, Huimin .
JOURNAL OF HAZARDOUS MATERIALS, 2011, 189 (1-2) :265-272