A Microporous Copper Metal-Organic Framework with High H2 and CO2 Adsorption Capacity at Ambient Pressure

被引：105

作者：

Laessig, Daniel ^{[1
]}

Lincke, Joerg ^{[1
]}

Moellmer, Jens ^{[2
]}

Reichenbach, Christian ^{[3
]}

Moeller, Andreas ^{[2
]}

Glaeser, Roger ^{[1
]}

Kalies, Grit ^{[3
]}

Cychosz, Katie A. ^{[4
]}

Thommes, Matthias ^{[4
]}

Staudt, Reiner ^{[5
]}

Krautscheid, Harald ^{[1
]}

机构：

[1] Univ Leipzig, Fak Chem & Mineral, D-04103 Leipzig, Germany

[2] Inst Nichtklass Chem eV, D-04318 Leipzig, Germany

[3] Univ Leipzig, Fak Phys & Geowissensch, D-04103 Leipzig, Germany

[4] Quantachrome Instruments, Boynton Beach, FL 33426 USA

[5] Hsch Offenburg, Fak Maschinenbau & Verfahrenstech, D-77652 Offenburg, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 44期

关键词：

adsorption; coordination polymers; copper; metal-organic frameworks; microporous materials; CARBON-DIOXIDE; CRYSTAL-STRUCTURE; HYDROGEN STORAGE; BUILDING-BLOCKS; POROSITY; METHANE; LIGAND; SITES; SORPTION; BINDING;

D O I：

10.1002/anie.201102329

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Fully accessible: Uptakes of 9.2 mmol g-1 (40.5 wt %) for CO2 at 273 K/0.1 MPa and 15.23 mmol g-1 (3.07 wt %) for H2 at 77 K/0.1 MPa are among the highest reported for metal-organic frameworks (MOFs) and are found for a novel, highly microporous copper-based MOF (see picture; Cu turquoise, O red, N blue). Thermal analyses show a stability of the flexible framework up to 250 °C. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：10344 / 10348

页数：5

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