Simultaneous reinforcing and toughening of PTFE/glass fabric composites based on polyaniline/carbon microcapsule network

被引:0
作者
Zhang, Bin [1 ]
Jiang, Yujie [1 ]
机构
[1] Zhejiang Sci Tech Univ, Coll Mat & Text, Zhejiang Prov Key Lab Ind Text Mat & Mfg Tech, Hangzhou 310018, Zhejiang, Peoples R China
关键词
filled polymers; electrical conductivity; surface resistance; tensile strength; carbon; scanning electron microscopy; bending strength; fracture toughness; glass fibre reinforced plastics; mechanical properties; polyaniline-carbon microcapsule network; PANI-CB microcapsules; polytetrafluoroethylene-glass fabric composites; PTFE-GF composites; surface resistivity; CB; CARBON NANOTUBES; POLYMER; DISPERSION;
D O I
10.1049/mnl.2018.5118
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Through designing dispersed well and assembled orderly structures, a series of polyaniline (PANI)/carbon (CB) microcapsules were successfully synthesised. In the formation of the PANI/CB microcapsules, PANI/CB microcapsules were in good dispersion and ordered state, which resulted in exceptional mechanical properties and electrical conductivity for polytetrafluoroethylene (PTFE)/glass fabric (GF) composites. Here, the authors have developed the PTFE/GF composites that have not only tensile strength up to 21.5 MPa, but also toughness up to 17.5 MJ/m(3), and surface resistivity up to 5 x 10(8) cm, it is difficult to obtain by other methods. This was achieved by only assembled orderly and ordered arrangement for forming highly ordered network structures in an oriented direction, without introducing a third component or chemical cross-linker as in interfacial systems. More importantly, they believe that the design principles and processing strategies, which can be applied to other material systems to develop superconducting, strong and flexible materials.
引用
收藏
页码:1615 / 1620
页数:6
相关论文
共 20 条
[1]   High-dilution carbon-black/polymer composites: Hierarchical percolating network derived from Hz to THz ac conductivity [J].
Adriaanse, LJ ;
Reedijk, JA ;
Teunissen, PAA ;
Brom, HB ;
Michels, MAJ ;
BrokkenZijp, JCM .
PHYSICAL REVIEW LETTERS, 1997, 78 (09) :1755-1758
[2]  
Ajayan PM, 2000, ADV MATER, V12, P750, DOI 10.1002/(SICI)1521-4095(200005)12:10<750::AID-ADMA750>3.0.CO
[3]  
2-6
[4]   A review of vapor grown carbon nanofiber/polymer conductive composites [J].
Al-Saleh, Mohammed H. ;
Sundararaj, Uttandaraman .
CARBON, 2009, 47 (01) :2-22
[5]   ARCHITECTURAL PTFE-COATED GLASS FABRICS - THEIR STRUCTURE AND LIMITATIONS [J].
ANSELL, MP ;
HILL, CAS ;
ALLGOOD, C .
TEXTILE RESEARCH JOURNAL, 1983, 53 (11) :692-700
[6]   Tribological studies of glass fabric-reinforced polyamide composites filled with CuO and PTFE [J].
Bahadur, S ;
Polineni, VK .
WEAR, 1996, 200 (1-2) :95-104
[7]   A comprehensive picture of the electrical phenomena in carbon black-polymer composites [J].
Balberg, I .
CARBON, 2002, 40 (02) :139-143
[8]   Recent Advances in Research on Carbon Nanotube-Polymer Composites [J].
Byrne, Michele T. ;
Gun'ko, Yurii K. .
ADVANCED MATERIALS, 2010, 22 (15) :1672-1688
[9]  
Kato S., 1996, J STRUCT ENG B, V42, P369
[10]   Dispersion of single wall carbon nanotubes by in situ polymerization under sonication [J].
Park, C ;
Ounaies, Z ;
Watson, KA ;
Crooks, RE ;
Smith, J ;
Lowther, SE ;
Connell, JW ;
Siochi, EJ ;
Harrison, JS ;
Clair, TLS .
CHEMICAL PHYSICS LETTERS, 2002, 364 (3-4) :303-308