G Synthesis of 2-propylheptanol from 1-pentanal in a single pot using bi-functional ruthenium hydrotalcite catalyst in batch and flow reactors

被引：2

作者：

Sharma, Sumeet K. ^{[1
]}

Jasra, Raksh V. ^{[1
]}

机构：

[1] Reliance Ind Ltd, Reliance Technol Grp, Vadodara 391346, Gujarat, India

来源：

INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY | 2015年 / 54卷 / 04期

关键词：

Catalysts; Bifunctional catalysts; Hydrogenation; Aldol condensation; Ruthenium; Hydrotalcites; 1-Pentanal; METHYL ISOBUTYL KETONE; ONE-STEP SYNTHESIS; LAYERED DOUBLE HYDROXIDES; MIXED-OXIDE CATALYSTS; CONDENSATION-REACTIONS; ALDOL CONDENSATION; N-BUTYRALDEHYDE; BASE CATALYSTS; ANIONIC CLAYS; NOBLE-METALS;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ruthenium containing hydrotalcite (Ru-HT) has been synthesized and used as a bi-functional catalyst in batch and continuous flow fixed bed reactor for aldol condensation of 1-pentanal followed by hydrogenation of aldol condensation product in a single pot without changing the reaction conditions. Activated Ru-HT catalyst shows higher conversion of 1-pentanal (83%) than as-synthesized Ru-HT sample (59% conversion of 1-pentanal) for aldol condensation of 1-pentanal. Higher catalytic activity of activated Ru-HT catalyst is observed under solvent free conditions as compared to methanol as the solvent.

引用

页码：451 / 458

页数：8

共 31 条

[11] Catalyzed self-aldol reaction of valeraldehyde via a mechanochemical method [J].

Heintz, Andrew S. ;

Gonzales, Javier E. ;

Fink, Mark J. ;

Mitchell, Brian S. .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2009, 304 (1-2) :117-120

[12] One-step conversion of acetone to methyl isobutyl ketone over Pd-mixed oxide catalysts prepared from novel layered double hydroxides [J].

Hetterley, Robert D. ;

Mackey, Richard ;

Jones, James T. A. ;

Khimyak, Yaroslav Z. ;

Fogg, Andrew M. ;

Kozhevnikov, Ivan V. .

JOURNAL OF CATALYSIS, 2008, 258 (01) :250-255

[13] One-step synthesis of methyl isobutyl ketone catalyzed by palladium supported on niobic acid [J].

Higashio, Y ;

Nakayama, T .

CATALYSIS TODAY, 1996, 28 (1-2) :127-131

[14]

HUANG TJ, 1982, Patent No. 4339606

[15] Combined solid base/hydrogenation catalysts for industrial condensation reactions [J].

King, F ;

Kelly, GJ .

CATALYSIS TODAY, 2002, 73 (1-2) :75-81

[16] Efficient direct synthesis of 2-ethylhexanal from n-butyraldehyde and hydrogen using palladium modified base catalysts [J].

Ko, AN ;

Hu, CH ;

Chen, JY .

APPLIED CATALYSIS A-GENERAL, 1999, 184 (02) :211-217

[17] Highly selective Pd/KX catalysts for low-pressure one-step synthesis of 2-ethylhexanal from n-butyraldehyde and hydrogen [J].

Ko, AN ;

Hu, CH ;

Yeh, YT .

CATALYSIS LETTERS, 1998, 54 (04) :207-210

[18] Na promotion of Pd/MgO catalysts for low-pressure one-step synthesis of MIBK from acetone plus H-2 [J].

Lin, KH ;

Ko, AN .

APPLIED CATALYSIS A-GENERAL, 1996, 147 (02) :L259-L265

[19] The "one-pot" synthesis of 4-methyl-2-pentanone (methyl isobutyl ketone) from acetone over PdCu catalysts prepared from layered double hydroxides [J].

Martínez-Ortiz, MD ;

Tichit, D ;

Gonzalez, P ;

Coq, B .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2003, 201 (1-2) :199-210

[20] Acetone transformation into methyl isobutyl ketone over Pt/HMFI catalysts.: IV.: Effect of density and strength of the acidic sites [J].

Melo, L ;

Giannetto, G ;

Cardozo, L ;

Llanos, A ;

García, L ;

Magnoux, P ;

Guisnet, M ;

Alvarez, F .

CATALYSIS LETTERS, 1999, 60 (04) :217-222

← 1 2 3 4 →