Modern mass spectrometry for studying mass-independent fractionation of heavy stable isotopes in environmental and biological sciences

被引：41

作者：

Epov, Vladimir N. ^{[1
]}

Malinovskiy, Dmitry ^{[2
]}

Vanhaecke, Frank ^{[2
]}

Begue, Didier ^{[3
]}

Donard, Olivier F. X. ^{[1
]}

机构：

[1] CNRS, Lab Chim Analyt Bioinorgan & Environm, Inst Pluridisciplinaire Rech Environm & Mat, UPPA,UMR 5254, F-64053 Pau, France

[2] Univ Ghent, Dept Analyt Chem, B-9000 Ghent, Belgium

[3] CNRS, Equipe Chim Phys, Inst Pluridisciplinaire Rech Environm & Mat, UPPA,UMR 5254, F-64053 Pau, France

来源：

JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY | 2011年 / 26卷 / 06期

关键词：

PRECISE DETERMINATION; RATIO MEASUREMENTS; EXCHANGE REACTION; MERCURY ISOTOPES; HG ISOTOPES; CADMIUM; PHOTOLYSIS; SEPARATION; FIELD; PHOTOREDUCTION;

D O I：

10.1039/c0ja00231c

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

This is the first review to focus specifically on the application of modern mass spectrometry techniques for studying mass-independent or anomalous isotope fractionation for 'heavy' elements. This review covers a period of ten years, starting from 2000. In the first part of the manuscript, we address theoretical aspects of mass-independent isotope fractionation, such as nuclear volume and nuclear spin effects. Secondly, most published articles on this topic to date are reviewed. Mass-independent isotope fractionation was determined by ICP-MS, MC-ICP-MS or TIMS for nineteen elements so far: Hg, Sn, Cd, Zn, Te, Sr, Pb, Cr, U, Ti, Ni, Mo, Ru, Ba, Nd, Sm, Gd, Yb and Hf, as reported in about fifty publications. In addition, mass-independent fractionation was observed for some other elements, silicon, germanium and sulfur, by other techniques.

引用

页码：1142 / 1156

页数：15

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