共 11 条
- [11] *STOE CIE, 2005, XAREA XRED32 XSHAPE
(+)-{1,2-Bis[(2R,5R)-2,5-diethylphospholan-1-yl]ethane-κ2P,P′}(η4-cycloocta-1,5-diene)rhodium(I) tetrafluoridoborate
被引：0
作者：
Schulz, Stefan
[1
]
Fischer, Christian
[1
]
Drexler, Hans-Joachim
[1
]
Heller, Detlef
[1
]
机构：
[1] Univ Rostock, Leibniz Inst Katalyse eV, D-18059 Rostock, Germany
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
|
2010年
/
66卷
关键词：
HYDROGENATION;
PRECATALYSTS;
CATALYSIS;
OLEFINS;
D O I：
10.1107/S1600536810039577
中图分类号：
O7 [晶体学];
学科分类号：
0702 ;
070205 ;
0703 ;
080501 ;
摘要：
The title compound, [Rh(C8H12)(C18H36P2)]BF4, exhibits a rhodium(I) complex cation with a bidentate bisphosphine ligand and a bidentate eta(2),eta(2)-coordinated cycloocta-1,5-diene ligand. The ligands form a slightly distorted square-planar coordination environment for the Rh(I) atom. An intramolecular P-Rh-P bite angle of 83.91 (2)degrees is observed. The dihedral angle between the P-Rh-P and the X-Rh-X planes (X is the centroid of a double bond) is 14.0 (1)degrees. The BF4 anion is disordered over two positions in a 0.515 (7):0.485 (7) ratio.
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页码：M1370 / U325
页数：11
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