Separating and recovering lithium from brines using selective-electrodialysis: Sensitivity to temperature

被引:55
作者
Zhao, Li-Ming [1 ,2 ,3 ]
Chen, Qing-Bai [1 ,2 ,3 ]
Ji, Zhi-Yong [1 ,2 ,3 ]
Liu, Jie [1 ,2 ,3 ]
Zhao, Ying-Ying [1 ,2 ,3 ]
Guo, Xiao-Fu [1 ,2 ,3 ]
Yuan, Jun-Sheng [1 ,2 ,3 ]
机构
[1] Hebei Univ Technol, Engn Res Ctr Seawater Utilizat, Minist Educ, Sch Chem Engn & Technol, Tianjin 300130, Peoples R China
[2] Hebei Univ Technol, Natl Local Joint Engn Lab Chem Energy Saving Proc, Sch Chem Engn & Technol, Tianjin 300130, Peoples R China
[3] Hebei Collaborat Innovat Ctr Modern Marine Chem T, Tianjin 300130, Peoples R China
基金
中国国家自然科学基金;
关键词
Lithium; Brine; Selective-electrodialysis; Coexisting cation; Temperature; ION-EXCHANGE MEMBRANES; MONOVALENT; SURFACE; ADSORPTION; WATER; NF; EXTRACTION; RADII; SALTS; ANION;
D O I
10.1016/j.cherd.2018.10.009
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
This work was to investigate the lithium ion fractionation from various binary cation systems at various operating temperatures by electrodialysis (ED) with monovalent selective ion exchange membranes (usually called selective-electrodialysis, S-ED). Then a ternary cation system was selected to verify the results obtained from the binary cation systems. In Li+-Mn+ (Mn+: Na+, K+, Mg2+, Ca2+) brines containing only one kind of anion-Cl-, higher efficient recovery of lithium was obtained at higher temperature than at lower one, and the separation coefficients (FM-Li ) at the same lithium recovery ratio were found to be changed slightly with temperature ranging from 10 degrees C to 30 degrees C. The results indicate the relationship between transport enhancement/interionic separation effects and temperature could be preliminarily expressed by Arrhenius-type equation. Moreover, the pore size of membrane and the cationic hydration number were analyzed with temperature increase, and then that FM-Li had little variation caused by temperature was explained. It should attribute to the swelling of membrane and a small reduction of cationic hydration numbers. Further verification was done in Li+-Na+-Mg2+ cation system, and the same results were obtained. The investigation experimentally demonstrates that S-ED technology is feasible for separating and recovering lithium from brines in different regions with different environment temperatures. (C) 2018 Institution of Chemical Engineers. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码:116 / 127
页数:12
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