Effects of montmorillonite on the properties of cross-linked poly(vinyl alcohol)/boric acid films

被引:38
作者
Chen, Chenwei [1 ,2 ,3 ]
Chen, Youji [2 ]
Xie, Jing [1 ,2 ,3 ]
Xu, Zhewei [2 ]
Tang, Zhipeng [2 ]
Yang, Fuxin [1 ,2 ,3 ]
Fu, Kaijia [2 ]
机构
[1] Shanghai Ocean Univ, Inst Packaging Engn, Shanghai 201306, Peoples R China
[2] Shanghai Ocean Univ, Colleague Food Sci & Technol, Shanghai 201306, Peoples R China
[3] Shanghai Engn Res Ctr Aquat Prod Proc & Preservat, Shanghai 201306, Peoples R China
关键词
Poly(vinyl alcohol); Montmorillonite; Boric acid; properties; packaging film; LAYERED DOUBLE HYDROXIDES; NANOCOMPOSITE FILMS; ANTIMICROBIAL PROPERTIES; BARRIER PROPERTIES; THERMAL-PROPERTIES; POLYVINYL-ALCOHOL; STABILITY; LINKING; BLENDS; PVA;
D O I
10.1016/j.porgcoat.2017.06.003
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The cross-linked poly(vinyl alcohol)/boric acid(PVA/BA) films incorporated with montmorillonite (MMT) was developed via a solution blending-casting method. The effects of MMT concentrations of 0%, 1%, 3%, 5% and 7% on the structural, mechanical, barrier, water resistance, thermal stability and morphology properties of cross linked PVA/BA film was investigated. It was found that the properties of the films changed as the MMT content varied. As the MMT content increased from 0% to 3%, the tensile strength increased, while the oxygen permeability and water vapour permeability reduced. However, these properties deteriorated slightly due to partially aggregations of MMT in the PVA film structure with increasing MMT content from 5% to 7%. The results showed the films incorporated with MMT became a little darker and tendency toward yellowness, the opacity increased, the water resistance and thermal stability was improved with the increasing amount of MMT. X-ray diffraction patterns, transmission electron microscopy (TEM) and scanning electron microscope (SEM) results revealed that the MMT was well dispersed in the PVA matrix and it was predominantly exfoliated. The cross linked PVA/BA film incorporated with 3% MMT showed the best comprehensive properties among all films.
引用
收藏
页码:66 / 74
页数:9
相关论文
共 57 条
[1]   Processing, Properties, and Applications of Polymer Nanocomposites Based on Layer Silicates: A Review [J].
Alateyah, A. I. ;
Dhakal, H. N. ;
Zhang, Z. Y. .
ADVANCES IN POLYMER TECHNOLOGY, 2013, 32 (04)
[2]   Physicochemical properties of starch-CMC-nanoclay biodegradable films [J].
Almasi, Hadi ;
Ghanbarzadeh, Babak ;
Entezami, Ali A. .
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 2010, 46 (01) :1-5
[3]   FTIR-ATR studies of the sorption and diffusion of acetone:water mixtures in poly(vinyl alcohol)-clay nanocomposites [J].
Breen, Alastair F. ;
Breen, Chris ;
Clegg, Francis ;
Doeppers, Leena-Marie ;
Khairuddin ;
Labet, Marianne ;
Sammon, Chris ;
Yarwood, Jack .
POLYMER, 2012, 53 (20) :4420-4428
[4]   Chitosan/clay films' properties as affected by biopolymer and clay micro/nanoparticles' concentrations [J].
Casariego, A. ;
Souza, B. W. S. ;
Cerqueira, M. A. ;
Teixeira, J. A. ;
Cruz, L. ;
Diaz, R. ;
Vicente, A. A. .
FOOD HYDROCOLLOIDS, 2009, 23 (07) :1895-1902
[5]   Mechanism of reinforcement in a nanoclay/polymer composite [J].
Chan, Mo-lin ;
Lau, Kin-tak ;
Wong, Tsun-tat ;
Ho, Mei-po ;
Hui, David .
COMPOSITES PART B-ENGINEERING, 2011, 42 (06) :1708-1712
[6]   Development of immobilized lysozyme based active film [J].
Conte, A. ;
Buonocore, G. G. ;
Sinigaglia, M. ;
Del Nobile, M. A. .
JOURNAL OF FOOD ENGINEERING, 2007, 78 (03) :741-745
[7]   Preparation and characterization of chitosan/poly(vinyl alcohol) chemically crosslinked blends for biomedical applications [J].
Costa-Junior, Ezequiel S. ;
Barbosa-Stancioli, Edel F. ;
Mansur, Alexandra A. P. ;
Vasconcelos, Wander L. ;
Mansur, Herman S. .
CARBOHYDRATE POLYMERS, 2009, 76 (03) :472-481
[8]   The thermal degradation of poly(methyl methacrylate) nanocomposites with montmorillonite, layered double hydroxides and carbon nanotubes [J].
Costache, Marius C. ;
Wang, Dongyan ;
Heidecker, Matthew J. ;
Manias, E. ;
Wilkie, Charles A. .
POLYMERS FOR ADVANCED TECHNOLOGIES, 2006, 17 (04) :272-280
[9]   Synthesis of boron nitride from boron containing poly(vinyl alcohol) as ceramic precursor [J].
Das, M. ;
Ghatak, S. .
BULLETIN OF MATERIALS SCIENCE, 2012, 35 (01) :99-102
[10]   The Dependence of the XRD Morphology of Some Bionanocomposites on the Silicate Treatment [J].
Dimonie, Doina ;
Constantin, Radovici ;
Vasilievici, Gabriel ;
Popescu, Maria Cristina ;
Garea, Sorina .
JOURNAL OF NANOMATERIALS, 2008, 2008